二乙酸甘油酯封端的齐聚L_丙交酯增塑改性聚L_丙交酯薄膜.pdfVIP

Vol. 22 No.4 2009 12 Journal of Functional Polymers 373 L L 郭其魁, 桂宗彦, 龚飞荣, 程树军, 陆 冲 (华东理工大学材料科学与工程学院,超细材料制备与应用 育部重点实验室, 上海200237) : 以二乙酸甘油酯(GD) 引发L丙交酯( LL ) 开环聚合合成了二乙酸甘油酯封端的齐聚 L丙交酯( OGL ) , 并以此为增塑剂, 以溶液共混法制备了 OGL 与高分子量聚L 丙交酯 (PLL ) 的共混膜采用DSC 研究了共混膜的T g 和结晶性变化, 考察了共混膜的力学性能和渗 出性结果表明: 随着OGL 含量的增加, 共混物T g 下降, 结晶度降低, 柔性提高; 与聚乳酸相比, 随着OGL 含量的增加, 拉伸强度弹性模量有 一定程度降低, 但断裂伸长率有较大程度的提高, 力学性能得到较好的平衡;OGL 增塑体系与GD 增塑体系相比较, 优势在于避免了小分子增塑 剂的渗出 : 聚丙交酯; 二乙酸甘油酯;封端; 改性;生物相容性 : TQ225.4 : : 2009 Properties of Poly( Llactide) Plasticized with Glycerol DiacetateTerminated Low Molecular Weight Poly( Llactide) GUO Qikui, GUI Zongyan, GONG Feirong, CHENG Shujun, LU Chong (Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and T echnology, Shanghai 200237, China) Abstract Glycerol diacetate (GD) terminated poly(Llactide) ( OGL ) were successfully synthesized by Glycerol diacetate initiated ringopening polymerization of Llactide, which was used as a biocompatible plasticizer for high molecular polylactide ( PLL ) . The differences of T g and crystallinity were analyzed with DSC and the mechanical property and effusion was illustrated as well. T he experiment results showed that stiffness, T g and the degree of crystallinity decreased with the increasing of OGL content, while the toughness enhanced. T ensile strength and Youngs modulus declinewith the increasing of OGL content, but the elongation at break improved. Plasticizer effusion was also avoided. Key words polylactide; glycerol diacetate; terminated; modification; biocompatibility L( PLL ) , [ 12] LPLL ,