超支化环氧树脂的合成及其改性环氧树脂导热胶性能研究 Synthesis of Hyperbranched Epoxy Resin and Properties of Modified Heat Conductive Epoxy Adhesive.pdfVIP

绝缘材料2012，45(1) 付继芳等：超支化环氧树脂的合成及其改性环氧树脂导热胶性能研究 超支化环氧树脂的合成 及其改性环氧树脂导热胶性能研究 付继芳，施利毅，钟庆东，陈立亚，陈 怡，丁郭君 (上海大学纳米科学与技术研究中心，上海200444) 摘要：以偏苯三酸酐(TMA)和二缩三乙二醇(TEG)为原料合成了端基为两个羧基、一个羟基的AB：型单体，用 TMA为核，采用一步法制备了新一代超支化聚酯，然后在相转移催化剂下与环氧氯丙烷反应进行端基环氧功 能化制备了超支化环氧树fJ旨HTTE．1。利用HTTE．1与A1：0，纳米粒子复合改性环氧树脂制备纳米复合材料， 并对其性能进行了研究。结果表明：所得三元纳米复合材料体系的韧性优于单独填充纳米粒子体系，热导率 提高。 关键词：超支化环氧树脂；增韧；热导率 中图分类号：TM215文献标志码：A 文章编号：1009．9239(2012)01．0001—05 of Resinand HyperbranchedEpoxy Properties Synthesis ofModifiedHeatConductiveAdhesive Epoxy Fu LiYa，Chen GuoJun Jifang，ShiLiyi，ZhongQingdong，ChenYi，Ding and Research (Nano—scienceTechnologyCenter,ShanghaiUniversity,Shanghai200444,China) trimellitic raw mono— AB2 Abstract：Usinganhydride(TMA)andtriethyleneglycol(TEG)asmaterials，An metwithtwo andone asend was TMAas carboxylgroups hydroxylgroup groups synthesized．Using was then nucleus，lowviscosityhyperbranchedpolyesterprepared，andhyperbranchedepoxyresin(HTTE一1) with under nano—tom- was transfer conditions．A byreactingepichiorohydrinphase catalysis synthesized was from resinmodifiedHTTE-1and the ofthena— nano-A1203，and posite preparedepoxy by properties werestudied．Theresultsshowthatthe andthermal ofthena— no—composite impactstrength conductivity