焦油深加工（Tar processing）.doc

焦油深加工（Tar processing） Coal tar and deep processing information Section 1 formation and properties of coal tar Coal tar is a black or dark brown viscous liquid produced during the coal distillation, or tar. Coal tar is divided into low temperature tar and high temperature tar. Carbonization relative density is small, the composition of alkane, olefin and aromatics accounted for about 50%, phenols content can reach 30%, the rest of pyridine bases of nitrogen compounds, sulphur compounds and colloidal substances, also contains a lot of paraffin in the coal tar. High temperature tar is the product of the second decomposition of low temperature tar in high temperature, and the tar in modern coking production is high temperature tar. High temperature tar is mainly composed of aromatic hydrocarbon, its yield, quality and composition depend on the properties of coking coal and the operating conditions in coking process. The production of coking coal is light, the volatile content of coal is high, the temperature of the beginning softening is low, the temperature of the colloidal state is long, and the tar yield is large. In coke oven operation ways and the furnace wall temperature increased and the roof space temperature increased, would lead to pyrolysis tar components, reduce the tar production rate, high temperature products of tar, anthracene, naphthalene, bitumen and free carbon content increases, density increases, phenols and neutral oil content is lower. The lack of coal in the carbonized chamber and the coke overshoot are equivalent to increasing the temperature of the roof space and the furnace wall. In addition, the yield and composition of the tar are also affected by the pressure system of the coking furnace. Generally, the yield of coal tar (yield) is about 3% to 4% of furnace coal. Estimates that tens of thousands of kinds of organic matter in coal tar, the vast majority of the part is with side chain ring, fused ring compounds and oxygen, sulfur and nitrogen