溶解热的测定（Determination of solution heat）.doc

溶解热的测定（Determination of solution heat） Determination of solution heat [applicable objects] pharmaceutical, pharmaceutical preparation, Chinese pharmaceutical engineering, pharmaceutical engineering, Chinese medicine (international communication direction), biological engineering major [experimental study] 3 I. experimental purpose 1. Determination of the solubility of KNO3 in water by using the calorimetry method. 2. Master the basic principle and measurement method of temperature measurement. 3. To understand the basic principle of the determination of integral solution heat by calorimetry. 2. Experimental principle Substance dissolution is often accompanied by a thermal effect, which is called the dissolution of the substance. The solutes of matter usually include the destruction of solute lattice and solvation of solute molecules or ions. Among them, the destruction of lattice is often endothermic process, and the solvent is often used to exothermic process. The heat of dissolution is the sum of the heat of the two processes. And eventually its endothermic or exothermic, which is determined by the relative size of these two. Temperature, pressure, and the nature of the solute and solvent, dosage, is the significant factor affecting the solution heat, according to the change of the material in the process of dissolved solution concentration, solution heat into thickened solution heat and strong solution heat, thickened solution heat is also called the integral solution heat, is a mole under the condition of steady pressure substances dissolve in a certain amount of solvent to form a certain concentration of solution, inhaled or gives off heat, strong solution heat and differential solution heat, is a mole under the condition of steady pressure substances dissolved in a large number of a certain concentration of solution, the heat generated by the. Dosage of integral solution heat can be directly measured thermal method, differential solution heat can be obtained i