废料白银提取方法（Method for extracting waste silver）.docVIP

废料白银提取方法（Method for extracting waste silver） Waste silver extraction method 2010-9-29 14:07:43: small fonts [anonymous Internet] I want to comment (0) First, with the three wastes silver extraction. The so-called three wastes means: waste photographic fixer, silver waste liquid, semiconductor manufacturing tube processing waste semiconductor components, electrical connectors, silver plated scrap, mirror industry waste. Raw materials: around photostudios, hospital room, printing, electroplating factories, power plants, wireless electric switch factory, semiconductor components factory, mirror factory, waste recycling and other units to buy. The broken glass and hot water refill scrap pieces first silver etc.. With nitric acid solution for 2 - 3 hours, until the glass has no silver shell, and then filter the filtrate. With the same usage of waste fixative. Extraction method; (a) replacement method: using metal chemical activity is large, such as zinc, iron, aluminum, etc.. The replacement of silver from waste fixing solution. The usage is simple, directly added or inserted into the waste fixing bath with metal powder, metal and metal, silver has been attached to the metal surface replacement, but after replacement are impure, still need further purification. (two): the precipitation method with sodium sulfide fixer in silver, with silver sulfide to precipitate, the precipitate of silver sulfide into hot hydrochloric acid. And adding excess iron, make available silver. But the products need purification. The reaction is as follows: 2[Ag (S2O3) 2]3-+S-, Ag2S: +4S2O32- Ag2S+Fe+2HCI, Ag: +FeCI+H2S = Because of the toxic, operation should be carried out in a well ventilated place. (three) electrolysis method: direct extraction of silver, 1 times of treatment, for the quality of silver is very pure. Use correctly is very important in the two electrode electrolysis method. When energized, the cationic silver ions move, get electrons are reduced to silver atoms accumulated on