二氧化碳气化概述.docVIP

生物质二氧化碳气化综述 王燕杰1，应 浩1,2*，江俊飞1 （1. 中国林业科学研究院林产化学工业研究所；生物质化学利用国家工程实验室；国家林业局 林产化学工程重点开放性实验室；江苏省生物质能源与材料重点实验室，江苏 南京210042；2. 中国林业科学研究院 林业新技术研究所,北京 100091） 摘 要： 综述了温度、压力、催化剂和产物中CO的浓度等因素对生物质在CO2气氛中气化的影响。提高反应温度可以明显增加反应速率；压力的作用较复杂，反应过程中不仅受总压力的影响还受到反应物分压的影响；碱金属元素和碱土金属可以促进反应；根据反应机理，气体中CO含量过高会抑制反应的进行，减少反应中CO的分压和含量可以促进反应。展望了生物质CO2气化的应用前景。 关键词： 生物质；二氧化碳；气化；压力；催化 中图分类号：TQ35 文献标识码：A 文章编号：0253-2417（2003）00-0000-00 The Review of Biomass Carbon Dioxide Gasification WANG Yan-Jie1，YING Hao1,2，JIANG Jun-fei1 (1.Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. of Forest Chemical Engineering, SFA; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China; 2. Institute of New Technology of Forestry, CAF, Beijing 100091, China) Abstract: The effect of temperature, pressure, catalyst and the concentration of monoxide in product on biomass carbon dioxide gasification was reviewed. With the increase of temperature, the reactivity was accelerated dramatically. The effect of the pressure was complex for the reaction of gasification was influenced both by partial pressure of components and the whole pressure. Alkali metal and alkali earth metal can be used as catalysts for accelerating the reaction of biomass carbon dioxide gasification. According to the mechanism of carbon dioxide gasification, increasing the amount of monoxide inhibits the reaction to the favorable side, however, reducing the partial pressure and the amount of monoxide in the syngas can promote the reaction rate. The prospect of biomass carbon dioxide gasification application was also presented. Key words: biomass; carbon dioxide; gasification; pressure; catalysis 生物质作为一种清洁的、可再生的资源可以有效的代替或部分代替传统化石能源的使用[1]，约占全球总能源的10%～14%[2]并且可以解决偏远地区化石能源的运输和生物质资源浪费的 收稿日期：2012-12-07 基金项目：“十二五”国家科技支撑计划资助（2012BAA09B03） 作者简介：王燕杰（1990-），女，山东蒙阴人，硕士生，主要从事生物质热化学转化的研究 * 通讯作者：应浩，男，硕士生导师，研究领域为生物质能转化技术开发与工业应用；E-mail：