Nd3+掺杂对尖晶石型镍铁氧体吸波性能的影响 Influence of Nd3+dopant on the microwave absorbing properties of nickel spinel ferrite.pdfVIP

研究·分析·实验 Nd3+掺杂对尖晶石型镍铁氧体吸波性能的影响 郭 磊，余建华，李志军，王普红，丁志军，杜 斌 （防化研究院，北京102205 ） 摘 要：采用溶胶-凝胶法制备了Nd3+掺杂尖晶石型NiNd Fe O 镍铁氧体，借助同步热分析仪、X 射线衍 x 2-x 4 射仪、矢量网络分析仪对产物的结构及电磁参数进行了测试分析。通过匹配解析图求得样品最佳匹配厚度和最 佳匹配频率，同时利用传输线理论计算了最佳条件下样品的吸波性能。结果表明，生成镍铁氧体的处理温度不 能低于 1000℃，且当Nd3+掺杂量降到x=0.04 时，生成纯净的Nd3+掺杂镍铁氧体粉末。Nd3+掺杂量的变化对镍 铁氧体的电磁参数及吸波性能有较大影响，随Nd3+掺杂量减小，样品的匹配厚度及最小反射率峰值呈现逐渐减 小的趋势，吸收峰向高频移动。当x=0.02 时，最小反射率达－47dB ，小于－10dB 频宽达到4.5GHz 。 关键词：镍铁氧体；Nd3+掺杂；电磁参数；匹配厚度；吸波性能 + 中图分类号：TM25; TM277 .1 文献标识码：A 文章编号：1001-3830(2013)05-0019-04 Influence of Nd3+ dopant on the microwave absorbing properties of nickel spinel ferrite GUO Lei, YU Jian-hua, LI Zhi-jun, WANG Pu -hong, DING Zhi-jun, DU Bin Research Institute of Chemical Defense, Beijing 102205, China Abstract: Nd3+-doped nickel spinel ferrite were prepared by sol-gel method. The microstructural and electromagnetic properties were analyzed by TG-DSC, X-ray diffraction and vector network analyzer. Impedance matching solution maps is used to obtain the matching frequency and thickness. Based on the matching frequency and thickness, microwave absorption of the material was studied. The result shows that the annealing temperature should be higher than 1000 ℃and Nd3+-dopedt nickel spinel ferrite is prepared when the doping amount of Nd3+ is reduced to 0.04. It is found that the amount of Nd3+ dopant could affect the electromagnetic parameters and microwave absorbing properties of nickel ferrite. With decreasing doping amount, the matching thickness and minimum reflectance peak decrease gradually a