麦草碱木素酚化改性及其制备LPF 胶粘剂工艺研究 - 高校化学工程学报.PDF

21 4 No.4 Vol.21 2007 8 Journal of Chemical Engineering of Chinese Universities Aug. 2007 1003-9015(2007)04-0678-07 LPF , , ( , 510640) / (LPF)(FT-IR)(GPC) FT-IR GPC / / LPF LPF LPF PF 70 % LPF PF TQ 433.439 A Phenolation Modification of Wheat Straw Soda Lignin and its Utilization in Preparation of Lignin-Based Phenolic Formaldehyde Resins Adhesive LIU Gang-yong, QIU Xue-qing, XING De-song (School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: The lignin-based phenol formaldehyde (LPF) adhesive with high ratio of lignin to phenol and strong adhesive was prepared by using the wheat straw soda lignin (WSSL) phenolated in alkaline medium. The structural modification of WSSL via phenolation was studied by Fourier transform infrared (FT-IR) spectroscopy and gel permeation chromatography (GPC). The FT-IR spectra show that WSSL is phenolated, ester bond is cleaved and the content of methoxyl groups decrease. The GPC chromatograms of phenolated WSSL show that the average molecular weight decreases and the distribution region of molecular weight increases. The effects of the reaction parameters, such as the materia