PTFEFEVE氟碳防污涂层的表面特性与海藻附着.PDFVIP

第 23 卷 第 3 期 中 国 表 面 工 程 Vol.23 No.3 2010 年 6 月 CHINA SURFACE ENGINEERING June 2010 50 中 国 表 面 工 程 2009 年 doi: 10.3969/j.issn.1007−9289.2010.03.015 PTFE/FEVE 氟碳防污涂层的表面特性与海藻附着* 张占平，齐育红，刘 红 （大连海事大学材料科学与工程系，大连 116026 ） 摘 要：以 FEVE 氟碳树脂为成膜物、超细 PTFE 粉末为低表面能功能添加剂，试制了 PTFE 质量百分比分别为 10 %、 20 %、30 %的氟碳防污涂料，利用扫描电镜和表面形貌仪试验研究了涂层中 PTFE 含量对涂层表面形貌的影响，借助 生物学方法、体视显微镜和图像分析方法研究了涂层表面特性对海洋微藻（舟形底栖硅藻）和大型藻（水云藻）附着 的影响。结果表明，随着防污涂层中 PTFE 含量的增加，涂层的表面粗糙度降低，平滑性和致密性提高，涂层上底栖 硅藻和水云藻的附着量随之减少。 关键词：PTFE ；FEVE 氟碳树脂；生物附着；表面形貌；底栖硅藻；水云藻 中图分类号：O484.4; TB383 文献标识码：A 文章编号：1007–9289(2010)03–0070–04 Settlement of Marine Algae and Morphology of PTFE/FEVE Fluorocarbon Antifouling Coatings ZHANG Zhan–ping, QI Yu–hong, LIU Hong (Department of Materials Science and Engineering, Dalian Maritime Univ, Dalian 116026) Abstract: Fluorocarbon coatings were developed with respectively 10 %, 20 % and 30 % PTFE powder. Influence of content of PTFE on surface morphology of coatings was investigated using SEM and rugometer. It was studied that the effect of coating roughness on settlement of benthic diatom and Ectocarpus with stereo microscope by image process. Results indicated that with the increase of content of PTFE in paint, surface roughness of the the coating decreases, meanwhile, benthic diatom and Ectocarpus attaching onto the coating reduce. Benthic diatoms attached much more on horizontal specimen than on the vertical one, and they tend to settle onto the surface of the coatings that there are lots of micro–cracks. These results are helpful for developing new non–toxic antifouling paints. Key words: PTFE ; FEVE resin; biofouling; morphology; benthic diatoms; ectocarpus 0 引 言