溶解有机质在土壤及沉积物吸附多环芳烃类有机污染物过程中的作用.PDF

23 2 　　　　　 Vol.23, No.2 2003 3 ACTA SCIENTIAE CIRCUMSTANTIAE Mar., 2003 :0253-2468(2003)02-0216-08　　　:X131　　　:A 周岩梅, 刘瑞霞, 汤鸿霄　(, 　100085) :6 ———、、, 1H-NMR 6 , Freundlich (K ′), Freundlich (n)f , ., , logK ′f logK ow (K ow-)., . :;;; Influence of dissolved organic matter in sorption process of polycyclic aromatic hydrocarbons on soils and sediments ZHOU anmei, LIU Ruixia, TANG Hongxiao　(State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing　100085, China) Abstract:The sorption of polycyclicaromatichydrocarbons-naphthalene, phenanthrene and pyrene in six soil and sediment samples collected from Guanting Reservoir (Beijing, China)and its estuaries was investigated.The dissolved organic matters contained in these six soils and 1 sedimentswere characterized by H-NMRspectra.It is consideredthat the sorption capacities (K ′)are closelyinterrelated with thearomatici-f ty and nonpolar aliphaticity of dissolved organicmatter.TheFreundlich exponent (n)decreaseswith theincreaseof the polar group content in dissolved organic matter, but the role the polar aromatic component plays in sorption process is organic solvent.Furthermore, solute structure also influencesthe sorption and the relation between logK ′and logK (K is octanol-water partition coefficient)is linear.A fast sorption f ow ow model is established based on the amphiphilic property of dissolved organic matter and the resultsfrom experiment.However, it is difficult to apply this model to predict the sorption of nonpolar contaminants on natural sorbent. Keywords:dissolved organic matter;natural sorbent;polycyclic aromatic hydrocarbons;fast sorption model;