海水中有机锡含量测定方法研究.pdfVIP

32 1 Vol. 32, No. 1 2011 2 Journal of Hebei University of Science and T echnology eb.2011 : 2011) 周长杰, 刘 魁, 王荣耕, 李景印, 王云清 ( 河北科技大学理学院, 河北石家庄 050018) : 建立了氢化物发生顶空固相微萃取毛细管气相色 火焰光度检测器联用技术测定海水 中有机锡化合物含量的方法样品经NaBH4 衍生化后, 采用顶空固相微萃取装置萃取, 再用毛细 管气相色 火焰光度法测定氯化三 丁基锡的线性范围为40~ 200 ng/ L, 相关系数为0. 986 8 在 100, 140, 200 ng/ L 3 个添加水平下, 回收率为81.0% ~ 121. 0%, RSD 值为16. 98%, 检测限为 15 ng/ L该方法可用于海水中有机锡化合物的测定 : 氯化三 丁基锡; 顶空固相微萃取; 气相色 火焰光度法; 海水 : O657. 63 :A Study on determination of tributyltin in sea water ZHOU Changjie, LIU Kui, WANG Ronggeng, LI Jingyin, WANG Yunqing ( College of Sciences, Hebei University of Science and T echnology, Shijiazhuang Hebei 050018, China) Abstract: HSSPMEGC PD method w as developed for the determination of tributyltin in sea w ater. T he samples w ere deriv atived by NaBH , extracted by headspace solid phase microextraction and measured by gas chromatograph w ith flame photo 4 metric detector. T he calibration curve for tributyltin is linear in the range of 40 ~ 200 ng/ L and the correlation coefficient is 0.986 8 for tributyltin. On the three spiked levels of 100 ng/ L, 140 ng/ L and 200 ng/ L, the range of recovery is 81. 0% ~ 121.0% and RSD is 16.98% . T he detect ion limit of tributylt in is 15 ng/ L. The method is simple and feasible for the determi nation of organic compounds in sea w ater wit h satisfactory results. Key words: tributyltin; H SSPME; GC PD; sea w ater , , [ 1] , , , ( TBT ) , [ 2] ( 1 ng/ L) TBT , TBT : TBT ( BC ) 4 4 2 3 3 4 [ 34] 10 , BC 10 ~ 10 , BC