改性石墨用作锂离子蓄电池负极材料 study on modification graphite as anode for lithium ion battery.pdfVIP

综 述 改性石墨用作捏离子蓄电池负极材料 唐致远 吴 菲 9 (天津大学 化工学院 天津9 300072) 摘要 ：由于石墨作为负极材料的改性方法多种多样 所以重点探讨了什么样的方法更有效更可行 在论述各类改性方9 0 法的基础上9分析了其改性的内在原因 指出每种方法的不足之处 阐述了从中得到的一些启示 讨论了石墨选材对9 9 9 改性效果的影响 在对比所述各种方法后 认为掺杂或共改性是相对更好的改性途径9 9 0 关键词 ：锂离子蓄电池 石墨负极材料 改性 掺杂9 9 9 中图分类号 ：TM 912.9 文献标识码 ：A 文章编号 ：1002-087 X(2006)02-0 155-07 Study on modification graphite as anode for lithium ion battery TANG Zhi-yuan, WU Fei (Chemical Engineering School, Tianj in University, Tianj in 300072, China) The methods for modification of graphite as negative electrode is very diverse. The more effective and more practi- cable methods are the focus of this article. The various means for modification of graphite anode were reviewed. Moreover, the enhancing of electrochemical performance was analyzed and the existing disadvantages were proposedg some illumination was exhibitedg the influence on modification of different graphite materials were discussedg doping and co-modification were regarded as the much better approaches comparatively after comparing all of the methods above. lithium-ion secondary batteriesg graphite anodeg modification g doping 锂离子蓄电池作为绿色电池 其负极材料一直以来都是 机电解液与负极材料隔离开来 避免进一步反应 大大提高了 9 9 9 研究的热点 近年来人们不断研究出一些高比容量 高性能的0 \ 循环性能 虽然膜的形成会消耗电池中的锂并增加电极 电解