石煤提钒低温硫酸化焙烧矿物分解工艺-中国有色金属学报.PDFVIP

第 19 卷第 5 期 中国有色金属学报 2009 年 5 月 Vol.19 No.5 The Chinese Journal of Nonferrous Metals May 2009 文章编号：1004-0609(2009)05-0943-06 石煤提钒低温硫酸化焙烧矿物分解工艺 刘万里，王学文，王明玉，胡 健，张力萍 ( 中南大学 冶金科学与工程学院，长沙 410083) 摘 要：针对石煤提钒常压硫酸浸出能耗高、作业周期长的缺陷，提出石煤低温硫酸化焙烧矿物分解新工艺。以 贵州凯里石煤为原料，对石煤低温硫酸化焙烧的时间、焙烧温度、硫酸加入量以及焙砂水浸工艺参数进行研究。 结果表明：先对石煤进行低温硫酸化焙烧处理，再将焙砂按液固比 1.2 mL/g 加水于 100 ℃下搅拌浸出2 h ，钒的 浸出率可达 78.2% ；而在相同酸矿比和固液比的条件下，采用常压直接酸浸石煤时，在 100 ℃下搅拌浸出 48 h 后，钒的浸出率只有 67.8% 。石煤通过低温硫酸化焙烧可有效强化矿物分解过程，缩短提钒作业周期，提高酸的 利用率及钒的浸出率。 关键词：钒；石煤；矿物分解；硫酸化焙烧 中图分类号：TF 841.3 文献标识码：A Mineral decomposition process of vanadium recovery from stone coal by low temperature sulphating roasting LIU Wan-li, WANG Xue-wen, WANG Ming-yu, HU Jian, ZHANG Li-ping (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The new mineral decomposition process of vanadium recovery from stone coal by low temperature sulphating roasting was proposed, which overcomes the shortages of high energy consumption and long working cycle existing in stone coal decomposition with sulfuric acid solution under normal atmosphere. Using the stone coal obtained from Kaili of Guizhou Province, China, as raw material, the process parameters, such as roasting time, roasting temperature, sulfuric acid addition volume and the leaching with water for the calcine, were investigated. The results show that when the stone coal is firstly treated by low temperature sulphating roasting, then the obtained calcine is leached in water with liquid-to-solid ratio of 1.2 mL/g