超临界水解制备TiO2微粒过程的实验研究 - Bowen Publishing.PDF

Vol.2 No.1 Scientific Journal of Materials Science Mar.2012 超细微粒ZrO2 的超临界水解制备实验研究* 刘学武，汤洁 大连理工大学 化工机械学院，辽宁 大连 116012 摘 要：氧化锆（ZrO2 ）微粒作为电子陶瓷、功能陶瓷、结构陶瓷等高新科技领域方面的主要原料，应用前景十分广阔。超 临界水解制备金属氧化物微粒过程是一种崭新的微粒制备技术，用此过程成功地制备了平均粒径为925nm 的ZrO2 球形微粒。 研究结果表明，产物为纯度很高的球形单斜相 ZrO2 微粒，微粒粒径较小、分散性较好、粒度分布较集中。实验系统考察了操 作压力、操作温度、系统总流量和支路流量比等过程参数对微粒粒径的影响：随操作压力的升高，微粒的粒径有比较明显的增 大；随操作温度的升高，微粒粒径明显增大；随系统总流量的增大，微粒的粒径变小；随支路流量比的增加，微粒的粒径略有 下降，但变化不大。 关键词： ZrO 微粒，超临界水解，过程参数，微粒粒径 2 Experimental Research on Supercritical Hydrolysis Preparation of Ultrafine Particle ZrO2 Xuewu Liu, Jie Tang College of Chemical Machinery, Dalian University of Technology, Dalian, Liaoning , China, 116012 Abstract: Because of the excellent specialties and wide uses in many fields, ZrO2 has a promising future. Supercritical hydrolysis is a new method to produce particles. ZrO2 particles were successfully obtained through this method. The resulting samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Particle-size Analyzer. The influences of procedure parameters (include pressure, temperature, total flux, and ratio of branch flux) on particle size were investigated at the sa me time. The results indicated that the particle size increased with an increase in the pressure and temperature, while that decreased with an increase in the total flux. Fine particles having an average particle diameter of 793nm were produced at such condition as 327K, 8MP a, total flux of 30SLM and ratio of branch flux of 3. Key words: Particle ZrO ; Supercritical Hydrolysis; Procedure Paramet