Chapter 19 BODIPY Laser dyes applied in （第十九章BODIPY染料激光应用于）.pdf

Applied Science Innovations Pvt. Ltd. Chapter 19 BODIPY Laser dyes applied in sensing and monitoring environmental properties Jorge Bañuelos *, Fernando Lopez Arbeloa, Teresa Arbeloa, Virginia Martinez, and Iñigo López Arbeloa Departamento de Química Física, Universidad del País Vasco UPV / EHU, Apartado 644, 48080-Bilbao, Spain (* Corresponding Author, Phone : +34-946012711, Fax : +34-946013500, E mail : jorge.banuelos@ehu.es ). Content : 1. Introduction 2. General Photophysics of BODIPY Dyes 2.1. Effects of 2− and 6−Alkyl Groups 2.2. Solvent Effect 2.3. Photophysics in Solid Polymeric Materials 2.4. Red−shifted BODIPYs 3. Intramolecular Energy Transfer Processes: Multichromophoric BODIPY Systems 4. Charge Transfer Excited States: Cyano−BODIPY Dyes 5. Proton Sensor BODIPY Dyes 5.1. Charge Transfer Complex: Amino−BODIPY Derivative 5.2. Photoinduced Electron Transfer Processes in BODIPYs 6. Conclusions 7. Acknowledgements 8. References 1. Introduction : Fluorescent dyes have been intensively studied by the scientific community in multidisciplinary areas. The technological interest of these dyes has allowed their successfully application as active media of tunable lasers, in the development of photoelectronic devices, as fluorescent probes and chemical sensor, or monitoring the physicochemical characteristics of the surround- ing ambiences [1 − 7]. The understanding of the photophysical properties of these systems is of capital importance, not only because of the intrinsic potential applications but also in the design of new dyes with specific properties. Indeed, a satisfactory correlation between the photophysi- cal properties and lasing characteristics of several laser dyes has been established [8 − 16] by changing the molecular structure of the chromophore (substituent effect) and the environmental conditions