乙二醇双琥珀酸二甲基-戊醇酯磺酸钠的合成及性能-精细化工.DOC

已按照审稿专家的意见进行了修改，只是反应方程式放在引言中不知是否合适？ 201202090067 乙二醇双子琥珀酸2-乙基丁基酯磺酸钠的合成及性能 叶俊1，华平2*，喻红梅2，戴宝江3，方略韬1 (1．南通大学 纺织服装学院，江苏 南通 226019；2.南通大学 化学化工学院，江苏 南通226019；3.南通江山农药化工股份有限公司，江苏 南通 226006) 摘要：合成了乙二醇双琥珀酸2-基酯磺酸钠最佳工艺条件为：单酯化反应，n乙二醇:n(顺酐=1.00:2.10，催化剂用量为顺酐量的%，100℃反应.7h，酯化率9%(质量分数)；双酯化反应，n2-乙基-1-醇:n(顺酐=1.30:1.00，于210℃反应h，酯化率95.%(质量分数)；磺化反应，n亚硫酸氢钠:n(顺酐=1.05:1.00，于12℃反应磺化率100。CMC为mol/L，γCMC为27.96mN/m，乳化关键词：Gemini表面活性剂乙二醇双琥珀酸2-基酯磺酸钠Synthesis and properties of Ethylene glycol Gemini sodium 2-ethyl-1-butanol sulfosuccinate YE Jun1,HUA Ping2*, YU Hong-mei,DAI Bao-jiang 3,FANG Lve-tao1 (1.College of Textile and Clothing,，Nantong University， Nantong 226019；2.College of Chemistry and Chemical Engineering，Nantong University，Nantong 226019，China;3. Nantong Jiangshan Agrochemicals Co.,Ltd.，Nantong 226006,China) Abstract：Gemini sodium 2-ethyl-1-butanol sulfosuccinate was synthesized by the method of using carbonyl solid acid as the catalyst and without organic solvents in esterification and without any extra phase transfer catalysts in sulfonation at normal atmospheric pressure. The optimal synthetic conditions were as follows: in the single-esterification, n(ethylene glycol):n(maleic anhydride)=1.00:2.10, the amount of carbonyl solid acid was 2% of the amount of maleic anhydride, and reacted at 100℃ for 4.7h with the esterification rate of 99.21%(Mass fraction). In the di-esterification, n(2-ethyl-1-butanol):n(maleic anhydride)=1.30:1.00, and reacted at 210℃ for 1h with the esterification rate of 95.17%(Mass fraction). In the sulfonation, n(sodium hydrogen sulfite):n(maleic anhydride)=1.05:1.00, and reacted at 120℃ for 1h with the sulfonation rate of 100.65%( Mass fraction). The structure of the product was characterized by IR and 1HNMR. Its properties were measured: CMC=2.99×10-3mol/L , γCMC=27.96mN/m. Emulsifying power was 4.35min, permeability was 11.6s and the ability of hard water resistance was 13.3min. Keywords：GeminiGemini sulfosuccinate surfactant, Ethylene glycol Gemini sodium