氯离子在有机涂层中的渗透及涂层失效过程的电-IngentaConnect.PDF

52 / 2011 6 Penetration of Chlorine Ion in Organic Coat ing and Deterioration Process by Electrochemical Impedance Spectroscopy 1 1, 2 1 , , ( 1 , 10008 ; 2 , 10008 ) 1 1, 2 1 CHEN Jiacai , WA NG Xudong , SU N Dongbai ( 1 Center for Corrosion and Protection, University of Science and Technology Beijing, Beijing 10008 , China; 2 Beijing Key Laboratory for CorrosionErosion and Surface T echnology , Beijing 10008 , China) : ( EIS) : , ; , , EIS : , , 15 , . 5% ( ) NaCl : ; ; : T G 174. 4 : A : 10014 81(2011) Abstract : T he penetration law of chloride ion in the fluorocarbon separate coating and the deterioration process of fluorocarbon coating w ere investigated by permeability test and EIS, respectively. T he re sults show that the diffusion of chlorine ion in fluorocarbon separate coating have a time critical point. The spread of chlorine ion in coating reach a dynamic balance stage before the critical point, then the chlorine ion in coatings diffusion present linear increase trend. The permeability of chlorine ion in flu orocarbon coatings slow er than fluorocarbon resin layer. And solution and temperature on the infiltra tion of chloride ion in fluorocarbon coating have clear influence on the transmission. The EIS result al so indicates that the coating capacitance( Cc) all have ascendant trend. Besides, the artificial seaw ater had more corrosive effect than . 5% ( mass fraction) NaCl solution at 15 .