Al3Ti3CoCrCu05FeMoNi高熵合金激光涂层的研究.docVIP

Al3Ti3CoCrCu0.5FeMoNi高熵合金激光涂层的研究 温立哲，黄元盛 （江门职业技术学院 材料技术系，广东江门 529090） 摘要：使用激光熔覆制作了单相组成的Al3Ti3CoCrCu0.5FeMoNi合金涂层，通过退火处理使基体相析出二元金属间化合物，使用、X、显微硬度计分析了涂层的组织形貌、相结构和硬度。结果表明，激光熔覆制得的Al3Ti3CoCrCu0.5FeMoNi涂层由BCC单相组成，硬度为905.2 HV；在500 ℃以下退火处理，涂层的相组成不变。700 ℃以退火，涂层从BCC相中析出二元金属间化合物Al2Ti3相，析出相随退火温度升高逐渐长大。涂层硬度随退火温度的升高先降低后逐渐升高，Al2Ti3相析出导致涂层硬度升高。经过900 ℃退火后，涂层硬度达到938.8 HV超过了未退火时涂覆态的硬度。 关键词：高熵合金；Al3Ti3CoCrCu0.5FeMoNi激光熔覆；硬度TG113.25；TG146.2 文献标志码：A 文章编号：1007-7545（2017）06-0000-00 Study on Laser Coating of Al3Ti3CoCrCu0.5FeMoNi High-entropy Alloy WEN Li-zhe，HUANG Yuan-sheng (Material Technology Department, Jiangmen Polytechnic, Jiangmen 529090, Guangdong, China) Abstract：Al3Ti3CoCrCu0.5FeMoNi alloy coating composed of single phase was synthesized laser cladding. Two-element intermetallic compound was separated from matrix after annealing. The morphology, phase structure, and micro-hardness of coatings were analyzed by SEM, XRD, and microhardness tester. The results show that Al3Ti3CoCrCu0.5FeMoNi coating prepared by laser cladding is of BCC structure with hardness of 905.2 HV. BCC structure of coating remains when annealed at 500 ℃. After annealed at 700 ℃ above, Al2Ti3 precipitates from BCC parent phase of coating, and size of Al2Ti3 rises with increase of annealing temperature. Hardness value of coating drops firstly and then rises with increase of annealing temperature. Precipitation of Al2Ti3 results in rise of hardness of coating. After annealing at 900 ℃, hardness of coating is 938.8 HV, higher than that of non-annealed. Key words：high-entropy alloy; Al3Ti3CoCrCu0.5FeMoNi; laser cladding; hardness 自2014年叶均蔚团队[1]报道了高熵合金以来，高熵合金成为金属材料领域研究的热点。高熵合金因为高熵效应而显示出简单的相组成，主要是FCC相或BCC相[2-4]。很多高熵合金优异的综合性能，比如硬度高、抗高温氧化能力强、耐磨性好、在较高温度下仍然保持高硬度等[1,4]。 高熵合金主要真空熔炼[1]、真空溅射镀膜[4]、机械合金化[5]、激光熔覆[6]等方法制备。近年，激光熔覆法获得了较多的研究[7-10]。激光熔覆制备高熵合金涂层与其他方法相比，具有熔炼速度快技术工艺简单的特点，涂层厚度容易控制，相结构简单，与其他方法制的高熵合金相组成类似，主要由单一相或两种简单的相组成，并且主要的相为FCC相和BCC相[8-10]。在激光熔覆涂层时，可以在熔覆用金属元素粉末中添加稳定的高性能化合物如碳化钨[11]等，以进一步提高涂层性能。激光熔覆高熵合金涂层的性能范围宽阔，只需调节粉