H13钢550℃复合渗铬工艺研究.pdfVIP

下半月出版 MaterialHeat Treatment~材料热处理技术 H13钢550 oC复合渗铬工艺研究 龚 刚，曹辉亮。刘江文，焦东玲，罗承萍 (华南理工大学 机械工程学院，广东 广州5lO64O) 摘 要：通过光镜、扫描电镜、X射线能谱仪、X射线衍射仪和AUTOLAB电化学工作站研究了HI3钢在 540~560℃离子渗氮8 h再进行550℃低温盐浴复合渗铬后的表层相组织结构的转变。在550℃复合渗铬6h后 CrN化合物层平均厚度为5p,m，化合物层的显微硬度为l 500HV。渗铬层主要由最外层的CrN、中间的扩散层和 内部剩余的氮化物层组成。内部的氮化物层会随渗铬时间的延长而消失，转变的过程为6．Fe2N— ．Fe|N— ．Fe。 获得高硬度和强耐腐蚀性的表面层是由于生成了大量的细小的CrN晶粒。 关键词：低温复合渗铬；氮化铬；离子渗氮；耐腐蚀性 中圈分类号：TG156．8+8 文献标识码：A 文章编号：1001．3814(2008)04-0063．04 Study on Complex Chromizing at 550℃ f0r H13 Steel GONG Gang，CAO Huiliang，LIU Jiangwen，JL O Dongling，LUO Chengping (c0如 of Mech．and Eng．，South China Univers of Technology,Guangzhou 510640，China) Abstract：The phase microstructure transformations of H13 steel subjected by plasma nitriding at 540~560℃ for 8 h，followed by a salt bath thermoreacfive deposition and diffusion (TRD)chromizing process at 550℃ were investigated by means ofoptical microscopy,scanning electron microscopy(SEM)，X-ray energy dispersive spectroscopy (EDS)．X—ray diffraction and electric chemistry ofAI几1CII．AB．The results show that a CrN compound layer with an averagethickness of5 p．mandan averagemicrohardnessof1 500HVisformedinthe priorplasmanitrided compound layer by low-temperature chromizing at 55012for 6h．The chromized coating consis~ofthree sub—layers，i．e．namely the outerCrNlayer,theintermediate diffusionallayerandtheinner residualnitrided compoundlayer，the priornitrided compound layer with the inner sub—layer is vanishing as the chromizing time prolonging．The transformation course is 8-Fe2N 一Fe|N— —Fe．The hi【gh hardness and corrosion-resistant ofthe chromized coating are attributed to a large amountofthefineCrNgrainsonthe surfaceofcompoundlayer． Key words：low temperature complex chrornizing；chromi