氢氧化钾活化法制备淀粉活性炭电极材料-河北师范大学学报.PDF

36 / 1 / 河北师范大学学报/ / Vol. 36 No. 1 2012 1 JOURNALOFHEBEI NORMAL UNIVERSITY/ Natural Science Edition/ Ja n. 2012 氢氧化钾活化法制备淀粉活性炭电极材料* 1 2 2 钟玉兰, 王红强 , 李庆余 ( 1. , 545002; 2. , 541004) : KOH . : 2 850 e , 1.5 h, 2B 1. ( 1493. 9m / g) (218 F/g) . . ,300 mg/ g KOH , . :; ; + :TQ 424. 1 9 :A : 1000-5854( 2012)01-0067-05 Preparation of the Starch Actived Carbon for the Electrode Materials with KOH Activation 1 2 2 ZHO G Yulan , WA G Hongqiang , LI Qingyu (1. Group of Analysis, Liuzhou Chemical Industry Technical School, Guangx i Liuzhou 545002, China; 2. Chemistry and Chemical Engineering School, Guangxi ormal University, Guangxi Guilin 541004, China) Abstract:T he activated carbon for the electrodes in supercapacitors was fabricated from oxidized-crosslink- ing starch by chemical activation with potassium hydroxide. The activated carbons with best performance could be synthesized at thefollowing condition:activation temperature 850 e , m (KOH)Bm (C) is 2/ 1, and the activa- 2 tion time 1.5 h.In this condition,synthetical activated carbons presented higher BET surface area ( 1493. 9m / g) and high specific capacitance (218F/ g) .The pore structure of the starch activated carbon was assessed based on 2 at 77 K adsorption. The electrochemical performance of capacitors was determined using galv