氮掺杂石墨烯柔性薄膜的制备及其超电容性能-表面技术.PDF

第44卷摇 第1期 摇 摇 摇 表面技术 摇 摇 2015年01月 SURFACE TECHNOLOGY ·51· 試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試 氮掺杂石墨烯柔性薄膜的制备及其超电容性能 钟奇能,粟泽龙,李新禄 (重庆大学材料科学与工程学院,重庆400030) 摘摇 要: 目的摇 改善超级电容器用石墨烯薄膜的超电容性能。 方法摇 采用水热和高温热解法制备多孔 氮掺杂的石墨烯柔性薄膜,采用SEM形貌、XRD 图谱和等温曲线分析其结构,采用三电极体系测试循环 伏安曲线和恒流充放电曲线,分析其超电容性能。 结果摇 氮掺杂石墨烯柔性薄膜保持了氧化石墨烯的褶 皱透明,同时具有网络式的多孔洞结构。 氮气吸脱附测试表明,氮掺杂多孔石墨烯的比表面积为280.78 m / g。 氮掺杂石墨烯薄膜在1.0 mol/ L硫酸钠溶液中,当电流密度为0.1A/ g 时,其比容量达到169 F/ g。2 结论摇 氮原子的掺杂以及氮掺杂石墨烯柔性薄膜的多孔结构可以有效提高石墨烯材料的超电容性能。 关键词:氮掺杂石墨烯;多孔结构;超级电容器 中图分类号:TQ127.1;TM53摇 摇 摇 文献标识码:A摇 摇 摇 文章编号:1001鄄3660(2015)01鄄0051鄄05 Preparation and Supercapacitor Performance of a Flexible Nitrogen鄄doped Graphene Film ZHONG Qi鄄neng,SUZe鄄long,LI Xin鄄lu (School of Materials Science and Engineering,Chongqing University,Chongqing400030,China) ABSTRACT:ObjectiveTo improvethe electrochemical performanceof graphenefilmsfor supercapacitors. Methods Flexibleni鄄 trogen鄄doped graphene (N鄄doped graphene)films with porous structure were synthesized by hydrothermal and pyrolysis methods. The structureof theN鄄dopedgraphenefilmswereanalyzedby scanningelectronmicroscope (SEM),X鄄ray diffraction (XRD)and isotherms. The electrochemical capacitance of N鄄doped graphenefilmswas examined by three鄄electrode system test cyclic voltam鄄 metry and galvanostatic charge鄄discharge methods. Results The experiments indicatedthat theflexible N鄄doped graphenefilmsre鄄 tained thefolded and transparent characteristics of graphene oxide,and formed a three鄄dimensional porous structure as well. The 2 surface area of N鄄doped graphemewas measured to be