Sol鄄gel制备的Yb3+,Er3+掺杂光致发光膜及其.PDFVIP

第33卷摇 第9期 发摇 光摇 学摇 报 Vol郾33 No郾9 2012年9月 CHINESEJOURNAL OF LUMINESCENCE Sept. ,2012 Article ID:1000鄄7032(2012)09鄄1006鄄06 Sol鄄gel Preparation and Up鄄conversion Luminescence 3+ 3+ Properties of Er ,Yb Co鄄doped TiO Films 2 DONG Yan,WANG Pei,NIE Li鄄fang,ZOU Kai鄄shun,LIU Jun鄄cheng* (School of Materials Science and Engineering,Tianjin Polytechnic University,Tianjin300387,China) *Corresponding Author,E鄄mail:jchliu@ Abstract: 3+ 3+ Er ,Yb co鄄doped TiO films were successfully deposited on glass substrates by sol鄄gel method and 2 spin鄄coating technique. Ti(OBu) and lanthanide nitrateswere used as the starting materials,AcAc as the chelator 4 and nitric as the catalyzer. Thecontact anglebetweenthe solvent andtheglassewasmeasuredby contact anglegoni鄄 ometer. The thermal decomposition,the crystal structure,andthe morphology of thefilmswere investigated by ther鄄 mal analysis (TG),X鄄ray diffraction (XRD),andfield emission scanning electron microscopy (FE鄄SEM),respec鄄 tively. The results indicate that IPA is the suitable solvent to improvethe surfacewettingproperty. After annealed at 700 益 for2 h,both of the undoped and the co鄄doped films get good crystallinity,and the average grain size is not morethan50 nm. Thefilmontheglasssubstratewashighlycompact. Thestrongphotoluminescencephenomenonwas also observed. 3+ 3+ Key words:up鄄conversion;Yb ,Er co鄄doped;titanium oxide;sol鄄gel;spin coating CLCnumber:O482.31摇 摇 摇 Document code:A摇 摇 摇 DOI:10.3788/ fgxb20123