赛马霞石正长岩水热碱法分解反应动力学-硅酸盐学报.PDF

第 43 卷第 4 期 硅 酸 盐 学 报 Vol. 43 ，No. 4 2 0 1 5 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2015 DOI ：10.14062/j.issn.0454-5648.2015.04.24 赛马霞石正长岩水热碱法分解反应动力学 项 婷，杨 静，马鸿文，张 盼 ( 中国地质大学(北京)材料科学与工程学院，北京，100083) 摘 要：辽宁省赛马霞石正长岩的主要矿物有钾长石、钠沸石、黑云母和白云母，其中氧化钾含量超过10%，是制取钾盐的 重要原料。以氢氧化钠为碱性介质，对其进行了水热碱法分解实验。结果表明，霞石正长岩与 NaOH 水热分解反应的产物为 羟钙霞石，分解反应属于1 级反应；分解过程符合动力学方程 1–(1–x)1/3 ＝kt ，反应的表观活化能为Ea = 38.8 kJ/mol ；复合反 应体系中钠沸石的分解速率是影响正长岩分解反应的重要因素。 关键词：霞石正长岩；水热分解；羟钙霞石；动力学 中图分类号：TQ443.5 文献标志码：A 文章编号：0454–5648(2015)04–0519–07 网络出版时间：2015–04–01 16:15:07 网络出版地址：/kcms/detail/11.2310.TQ1615.021.html Kinetics of Decomposition Reactions of Saima Nepheline Syenite by Hydrothermal Treatment with Sodium Hydroxide Solution XIANG Ting , YANG Jing, MA Hongwen, ZHANG Pan (School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China) Abstract: The main minerals in a nepheline syenite from Liaoning, China, are potassium feldspar, natrolite, biotite and muscovite, which consist of more than 10% of K O content for the possible preparation of potash salts. The nepheline syenite was 2 hydrothermally decomposed using sodium hydroxide as an additive. The experimental results reveal that the decomposition product is hydroxycancrinite. The decomposition reaction belongs to first-order reaction. The decomposition process follows a kinetic equation of 1–(1–x)1/3 ＝kt, and the chemical reaction controls the decomposition process. The apparent activation energy E calculated is 38.8