纳米科技课题报告.ppt

翻译：汪洋龙 温有海 制作讲解：于明坤 二、Introduction 一、Abstract 三、Experimental 四、Results and discussion 目 录 CONTENTS 五、Conclusion CNPs was modified by the functionalization of aromatic amine(芳香胺） type and of amide-amine（氨基化合物） type. TEM：was used for investigation of surface – morphology of pristine and modified nano-particles. XPS：chemical composition of CNPs FTIR：chemical composition of CNPs BET：The total pore volume, surface area and pore size distribution It is shown that by the chemical modification the CNPs surface and pores within were grafted with nitrogen functional groups. 1、NPs:applied in heterogeneous catalysis, medicine, nano-electronics, optical communication and gas sensing. NPs possess large surface/volume ratio and a large fraction of surface atoms 2、CNPs: are composed of elemental carbon , in the form of nearly spherical particles with the diameters from10–100nm . CNPs having a large specific surface area,are hydrophobic in nature and strong cohesive forces occur between individual particles. 3、In this study, the functionalization of surface was used to activate CNPs. higher wettability , biocompatibility tissue engineering The first procedure of the CNPs modification, adapted from that already described in comprises two steps:1st nitration step(formation of –C–NO2 groups) and 2nd amine function (–C–NH2 formation). TEM、FTIR、XPS、BET The second procedure of the CNPs modification, adapted from that already describedin includes two following steps:1st oxidation step(formation of –COOH groups)and 2nd amide function formation. One can see that CNPs agregate and form chain structures It is also possible to estimate the CNP sizes which vary from 30–60 nm. There are no significant differences in the visible structure of CNPs before and after the chemical modification Chemical modification improves wettability of the CNPs surface and the increased wettability The FTIR results prove that nitrogen was chemically b