硫酸镁对湿式石灰石烟气脱硫过程的影响研究-环境科学学报.PDF

第 22 卷第 5 期 环 　境 　科 　学 　学 　报 Vol . 22 ,No . 5 2002 年 9 月 ACTA SCIENTIAE CIRCUMSTANTIAE Sep . ,2002 ( ) 文章编号 2002 　　　中图分类号 :X512 　　　文献标识码 :A 硫酸镁对湿式石灰石烟气脱硫过程的影响研究 1 2 2 ( 1. 青岛大学环境科学与工程系 ,青岛 　266071 ;2 . 浙江大学环境工程系 , 孙文寿 ,吴忠标 ,谭天恩 　 杭州 　310027) 摘要 : 以旋流板塔为吸收器 ,探讨了硫酸镁对湿式石灰石烟气脱硫过程浆液p H 值 、脱硫率及石灰石利用率等的影响. 实验表 明,硫酸镁能促进石灰石等的溶解 ,延缓浆液p H 值的下降 ,有效提高脱硫率. 依据实验结果 , 分析了过程机理 ,计算对比了 不同浓度硫酸镁强化下石灰石的利用率随p H 值的变化情况 ,综合考虑脱硫率和石灰石利用率等因素 ,确定适宜的p H 值操 作范围为 5 —6 . 关键词 :烟气脱硫 ;旋流板塔 ;硫酸镁 ;石灰石 ;二氧化硫 Effects of magnesium sulfate on wet limestone F GD process 1 2 2 ( SUN Wenshou , WU Zhongbiao , TAN Tianen 　 1. Department of Environmental Science and Engineering , Qingdao Univer sity , Qingdao 　266071 , China ; 2 . Department of Environmental Engineering , Zhejiang University , Hangzhou 　310027) Abstract :Wet FGD tests were conducted in a rotatingstream tray scrubber . Effects of magnesium sulfate on slurry p H value , SO2 removal effi ciency and limestone utilization were investigated. Experiments demonstrated that magnesium sulfate could promote limestone dissolution , slow down the descent of slurry p H value and effectively increase SO2 removal efficiency. According to experimental results , the process mechanism was analyzed and changes of limestone utilization with p H value were calculated and compared at different magnesium sulfate concentrations. Considering removal efficiency , utilization etc . , the adequate operating p H range was determined to be 5 —6 . Keywords :flue gas desulfurization ; rotatingstream tray scrubber ; magnesium sulfate ; limestone ; sul