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研磨-焙烧法制备BiOI/BiOBr异质结光催化剂及其光催化性能 薛霜霜1，何洪波1，吴 榛1，余长林,2*, 周晚琴1（1.江西理工大学冶金与化学工程学院，江西 赣州 341000； 2.福州大学能源与环境光催化国家重点实验室，福建，福州，350002） 摘要: 首先通过沉淀法制备BiOBr和BiOI纳米粉体，然后在主体BiOBr光催化剂中掺杂不同含量的共催化剂BiOI，充分研磨后在不同温度下进行煅烧3 h，制备了BiOI/BiOBr系列复合物，其中BiOI的质量分数分别为1%，2%，4%和8%。采用氮气物理吸附、X射线粉末衍射(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)、紫外-可见(UV-Vis)漫反射(DRS)和光电流测试等技术对所制备的样品进行表征。以酸性橙II为模拟污染物, 在可见光下考察了煅烧温度和BiOI复合含量对BiOBr主体光催化剂的光催化性能的影响。研究表明，当复合BiOI的含量为4%，煅烧温度为400℃时所制备的复合光催化剂表现出最高光催化性能，其降解效率分别是纯BiOBr和BiOI的1.7和1.9倍。复合BiOI促进了催化剂对可见光的吸收，同时经过研磨和煅烧形成的BiOI/BiOBr异质相结，促进了光生电子e-)和空穴h+)的分离，提高了光催化活性。 关键词：研磨; 煅烧；BiOI/BiOBr复合物；光催化；活性提高 Fabrication BiOI/BiOBr hetero-structured photocatalyts by grinding-calcination route and their photocatalytic performance XUE Shangshuang1, HE Hong-bo1, WU Zhen, YU Chang-lin1,2*, ZHOU Wan-qin1 (1. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Jiangxi Ganzhou 341000 China; 2. State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China) Abstract: Pure BiOBr and BiOI nanopowders were first synthesized by precipitation method. BiOBr main photocatalyt and BiOI cocatalyst with different contents were mixed and grinded. After grinding, the composite powder was calcined at different temperatures. The produced BiOI/BiOBr hetero-structured photocatalyts (BiOI content: 1 wt%, 2wt%, 4wt%, 8wt%) were characterized by N2-physical adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier translation infrared spectroscopy (FT-IR), and UV-Vis diffuse reflectance spectroscopy (DRS) and photoelectrochemical measurements. Acid orange II dye was selected as degradation target pollutant under visible light irradiation. The effects of BiOI coupling concentration and calcination temperature on the photocatalytic performance were investigated. Results showed that the BiOI/BiOBr composite photocatalyst with 4 wt% BiOI and calcination at 400℃ showed about 0.7 and 0.9 times increase in degradation