强超声场作用下掺钡纳米氧化镁的制备及其负载钌基氨合成催化剂的 .pdf

强超声场作用下掺钡纳米氧化镁的制备及其负载钌基氨合成催化剂的催 化性能 夏庆华，霍超，郑遗凡，刘化章 （浙江工业大学化材学院，浙江杭州 310032） 【摘 要】 运用功率超声技术共沉淀制备了掺钡纳米MgO载体，以RuCl 为前驱体，采用浸渍法制备了一系列钌基氨 3 合成催化剂。利用XRD和SEM等表征手段，考察了超声功率对掺钡纳米氧化镁及其负载 Ru 催化剂的表面形貌、物相的 影响，探讨了功率超声的作用机理，并在450~500 ℃的条件下评价了催化剂对氨合成的催化活性。研究结果表明，超声功 率是制备掺钡纳米MgO 的关键因素之一，适宜的超声功率不仅能改善催化剂的表面形貌，减小了掺钡纳米MgO载体的晶 粒度，同时可增强钡、镁之间的相互作用，使钡更均匀地分散于载体中，从而达到较佳的掺钡效果。当超声功率为480 W 时，催化剂在10 MPa，450 ℃和10000 h－1空速条件下，2 % Ru/Ba-MgO催化剂上的出口氨浓度达到8.12 % 。 【关键词】超声制备；掺钡纳米氧化镁；钌；负载型催化剂；氨合成 中图分类号: TG146 文献标示码： A Catalytic Performance of Ru Catalyst Supported on Ba-Doped nano-MgO Prepared in high intensity ultrasonic for Ammonia Synthesis Xia qinghua, Huochao, Zhengyifan, Liu Huazhang (College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032) 【Abstract 】 Ba doped nano-magnesia (Ba-MgO) was prepared by the chemical co-precipitation method in high intensity field , and a ruthenium catalyst was prepared by the impregnation method using the ultrasonic treatment of Ba-MgO as the supports, RuCl3 as the Ru precursor. The effects of ultrasonic power to the surface and matter posture of the Ru catalysts were characterized by XRD and SEM , the function mechanism of high intensity ultrasonic field are also discussed in this paper ,and the activity of Ru catalysts for ammonia synthesis was evaluated under the conditions of 10000 h-1, 10.0 MPa and 450-500℃. The results show ultrasonic power of preparation was one of the key factors, and a suitable ultrasonic power improved its surface performance and declined the conglomeration of particulate, at the same time, Ba was dispersed uniformly in the support and the pr