PPT - Yanming Xue, Synthesis and photoluminescence课件.ppt

Synthesis and photoluminescence characteristics of (Sr, Ca)3B2O6:Eu for application in white light-emitting diodes;content; A series of yellow–green (Sr, Ca)3B2O6:Eu phosphors have been synthesized using precursors prepared via a facile sol–gel route. The solid-solution phases crystallized to materials with the formula of Sr3-x-yCaxEuyB2O6 with varied Ca2+ and Eu2+ contents. The emission peak centered at 540 nm under near-UV excitation exhibited a broad-band distribution in the range of 450–650nm. The dependences of the luminescence intensity on the contents of Ca2+ substitution and Eu2+ dopant were also investigated. The composition in the host lattice sensitively affected the chromaticity index. Sr1.21Ca1.7Eu0.09B2O6 (SCB:0.09Eu) was shown to possess the highest intensity and broadest emission band. Calcining temperature was shown to greatly influence the luminescent properties of SCB:0.09Eu. It is concluded that SCB:0.09Eu can be used as an efficient yellow–green phosphor for white light-emitting diodes (white LEDs) applications.;Introduction;Borate-based phosphors with doping rear earth ions possess excellent properties To increase the efficiency of white LEDs, much attention has been paid to the development of not only LED chips but also new phosphors that exhibit better luminescence properties under the excitation in a wide near-UV region. So we could focus on the alkaline-earth metal borate compounds doped with Eu2+ for the desired targets. In our present work, the Sr3-x-yCaxEuyB2 O6 system have been initially investigated in depth for seeking to explore a highly efficient phosphors for applications in white LEDs by optimizing various controllable conditions. ;Experimental;;;;;Conclusions;Acknowledgements;;谊阮洒晌境册捉镑湃铜僳漫怯晋蛮仪抓印凳隧寓蛮帘荔杉周币品桔功轻吧PPT - Yanming Xue, Synthesis and photoluminescence课件PPT - Yanming Xue, Synthesis and photoluminescence课件