周双喜-矿物掺合料料对水泥浆体毛细孔壁亲水性影响.pdf

矿物掺合料对水泥浆体毛细孔壁亲水性的影响 周双喜，陈益民 （中国建筑材料科学研究总院，北京，100024） 摘要：为了研究矿物掺合料对水泥浆体收缩性能的影响，对掺有三种矿物掺合料不同掺量的 水泥浆体的亲水性进行了研究，利用改进的 Washburn 动态法测量掺有三种矿物掺合料水泥 浆体 7d 龄期的接触角，并用水银压入法测量水泥石的孔结构参数。研究结果表明，粉煤灰 和矿渣粉的掺入在一定程度上降低了水泥石内部毛细孔壁的亲水性，而硅灰的掺入则增加了 水泥石内部毛细孔壁的亲水性；与不掺掺合料的水泥浆体相比较，掺有矿物掺合料的水泥石 的孔分布向小孔径偏移。 关键词：矿物掺合料；接触角；亲水性；毛细孔 The influence of mineral additives on hydrophilic property of cement pastes capillary Zhou shuangxi, Chen yimin (China Building Materials Academy, Beijing, 100024) Abstract: In order to investigate the influence of mineral additives on shrinkage of cement pastes, a series of experiments were carried out to evaluate the hydrophilic property and pore structure parameters of cement pastes containing three mineral additives. The contracting angle of cement pastes with three mineral additives was measured by improving Washburn dynamic way, and pore size distribution was carried out using a mercury intrusion porosimeter (MIP). The results show that the hydrophilic property of cement pastes is descended when the paste containing fly ash or slag powder, while the hydrophilic property of cement pastes is increased when the paste containing silica fume. The pore size distribution of cement pastes is changed when adding mineral additives in the pastes. There appears much little size capillary in the cement pastes containing mineral additives. Key words: Mineral additive; contracting angle; hydrophilic property; capillary 混凝土的体积稳定性对混凝土的耐久性能有很大的影响。混凝土的体积稳定性不好，在 浇注完成之后，由于体积变化而在混凝土中产生内应力，当内应力达到一定水平时，会在混 凝土中的薄弱部位产生裂纹[1-2]，导致混凝土的力学性能降低，对结构安全性构成威胁；即 使混凝土整体力学性能没有明显下降，这些裂纹的存在也会使混凝土的抗渗性下降，给环境 [3-4] 介质的侵入提供了通道，导致混凝土的耐久性能降低 。 混凝土是由水泥、砂、石、水、外加剂、矿物掺合料组成的多相凝聚体，水泥石（硬化 水泥浆体）是将所有的