氢气中灼烧zns和卤化钾混合物制备zns基蓝光粉的研究 preparation of zns based blue phosphors by sintering zns with kalium halide as additive in argon gas.pdfVIP

32 张志刚：氩气中灼烧ZnS和卤钾混合制备ZnS基蓝光粉的研究 电工材料2009No．4 氢气中灼烧ZnS和卤化钾混合物制备 ZnS基蓝光粉的研究 张志刚 (桂林电子科技大学信息材料科学与工程系，广西桂林541004) 加对ZnS荧光粉发光性能的影响。用X射线衍射仪(XRD)、扫描电子显微镜(SEM)和荧光光谱仪 (FS)对样品进行表征。结果表明，在337am波长光激发下，添加卤化钾的ZnS荧光粉发射出明亮监 光，发射峰位于464nm处。随着KBr添加量的增大，荧光粉发光强度呈现先增大后减小的变化规律， KBr添加量为10％(原子分数)时荧光粉蓝光最强。 关键词：ZnS；蓝色荧光粉；卤化钾 中图分类号：TM23；0482．31文献标志码：A 文章编号：1671—8887(2009)04—0032—04 ofZnSBasedBlue Preparation PhosphorsbySintering ZnSWithKaliumHalideasAdditivein Gas Argon ZHANG Zhi—gang of MaterialScienceand (Departmentlnformation Engineering，GuilinUniversity Electronic 541004，China) of Technology，Guilin Abstract：ZnSbased withblueemissionwasfabricatedvia themixture phosphor sintering ofZnSandKX(X=Cl，BrorI)inAr amountsofKBrwhichwouldaffectthe gas．The ofZnS withKBrasadditivewerestudied．The properties phosphors photoluminescent werecharacterized mic- as-preparedsample byX-raydiffraction(XRD)，scanningelectron fluorescence results roscope(SEM)，andspectroscopy(FS)，respectively．Theexperimental indicatethatthe ofblueemissionwhichhasa of464amunderan intensity wavelength excitation of337amincreasesandthen withanincreaseofthe wavelength firstly drops amountsofKBr．andhasa maximumWhentheamountsofKBriS10at％