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间二氯苯及间氯甲苯的制备(Between two chlorobenzene and m-chlorotoluene preparation)
间二氯苯及间氯甲苯的制备(Between two chlorobenzene and m-chlorotoluene preparation)
This article is contributed by nnq1979
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Atmosphere, hydrogen
,,
VIP information
Preparation of two benzyl chloride between chlorobenzene and Chlorobenzene
/
The present invention relates to a process for the isomerization of an ortho aromatic chloride to an aromatic chloride through a zeolite
Ammonia benzene and toluene by chlorination, generally prepared two chlorobenzene and oxygen. A G product was a mixture of isomers, namely to ask a neighbor, or, two chlorobenzene and adjacent bit oxidation of toluene, the reported isomer in less. The result depends on the reaction conditions and anti false by using the catalyst. (Ullman chemical base 5, volume, page 3) and. The first edition of A633., two chlorobenzene and toluene chloride, is often used as a preparation for drug, crystal and implant protection. A corresponding two chlorine is required by isomerization of the ortho - and ortho - chlorides
One
Meat or ask chlorotoluene method. The fabrication process and economic system from the point of view, often using zeolite as catalyst for isomerization. (see patent D - A3363D 3276E - A66 and JE347, L - A400, P465P - 229P application No. 7 public chartered 577 = J5 143) 8430. of the patent of the method the defect is short catalyst life, after 200 hours of use must be regenerated. In the process of isomerization of aromatic oxide, hydrogen can be added. According to the D - A3363, E347 by ortho and para
Two different preparation of benzene oxygen citrate two chlorobenzene can be added when asked ammonia or hydrogen as diluent, to reduce the two oxygen partial pressure of benzene in gas phase, down 1 and 4 of the patent, in two per mole of chlorobenzene adding 4 mol and 53 mol of nitrogen. In the reaction of.5 spider out
After hours, the catalyst must
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