硫脲类阴离子受体的研究进展3.pdf

第 16 卷 第 5 期 化　学　进　展 Vol. 16 No. 5 2004 年 9 月 PROGRESS IN CHEMISTRY 　Sep. , 2004 硫脲类阴离子受体的研究进展 1 , 2 1 1 吴芳英 　温珍昌 　江云宝 ( 1 厦门大学化学系 现代分析科学教育部重点实验室 　厦门 361005 ; 2 南昌大学化学系 　南昌 330047) 摘 　要 　阴离子识别是超分子化学研究的重要内容之一 ,其关键环节是构筑可识别阴离子的结合受体 , 后者以非共价键力如静电作用、疏水作用、氢键等与阴离子结合。本文详细评述了近 5 年来硫脲类阴离子识 别受体的设计、结构及其阴离子识别作用的研究进展。 关键词 　硫脲衍生物 　阴离子受体 　阴离子识别 ( ) 中图分类号: O6227 ; O6413 　文献标识码 : A 　文章编号 : 1005281X 2004 Thioureabased Receptors for Anion Recognition and Sensing 1 , 2 1 1 Wu Fangying 　Wen Zhenchang 　Jiang Yunbao ( 1. Department of Chemistry and the MOE Key Laboratory of Analytical Sciences , Xiamen University , Xiamen 361005 , China ; 2. Department of Chemistry , Nanchang University , Nanchang 310047 , China) Abstract 　Anion recognition and sensing have been developed into an important research subject in supramolecular chemistry. Noncovalent interactions such as hydrogen bonding , electrostatic interaction , hydrophobic interaction , etc. are the most important binding forces existing in the anionreceptor binding complexes , which forms the basis of designing anion binding receptors. The design , construction and anion recognition and sensing of thioureabased receptors following mainly multi hydrogen bonding interactions are reviewed. 51 key references were cited to represent the related advances in the past 5 years. Key words 　thioureas ; anion receptor ; anion recognition ; anion sensing 　　阴离子在生物学、药学、催化和环境科学等研究