钐对铜电积用铅基阳极性能的影响.docVIP

钐对铜电积用基阳极性能的影响 朱茂兰，涂弢，朱根松，张丽娜，王瑞祥 （1.江西理工大学 应用科学学院，江西赣州341000摘要：采用二步重熔法制备了不同含量的Pb-Sm合金，含量合金力学性能、耐腐蚀性能和阳极电位。结果表明合金抗拉强度随含量增大而增大，当含量达到0.5%时，抗拉强度为13.9 MPa，比纯提高了21.9%，当含量超过1.0%，继续提高合金中含量，合金抗拉强度提高幅度减缓当合金中含量为0.5%时腐蚀速率纯增加了0.76%，不会对铅基阳极腐蚀性能产生明显影响合金电极稳定电位随含量的增加而减小。关键词：电积；Pb-Sm合金；力学性能；腐蚀性能；阳极电位 of Sm on Property of Pb-base Anode for Copper Electrowinning ZHU Mao-lan1,2, TU Tao1, ZHU Gen-song1, ZHANG Li-na1, WANG Rui-xiang1 (1. School of Applied Sciences, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China; 2. College of Chemistry and Materials Science, Longyan University, Longyan 364012, Fujian, China) Abstract: Pb-Sm alloy anodes with different Sm content were prepared by two step remelting process. The effects of Sm contents on tensile strength, corrosion resistance and anode potential of Pb-Sm anodes were investigated. The results show that tensile strength rises with increases of Sm content. With mass fraction of Sm of 0.5%, tensile strength of alloy reaches 13.9 MPa increased by 21.9% compared with pure lead anode. With Sm content exceeding 1.0%, the improving extent of tensile strength slows down. With mass fraction of Sm of 0.5%, corrosion rate of alloy rises by 0.76% compared with pure lead anode, which has no obvious effect on corrosion property of anode. The anode stable potential reduces with increase of Sm content. Key words: copper electrowinning; Pb-Sm alloy; mechanical property; corrosion resistance; anode potential 铜电积是湿法提铜的主要工序之一，电耗占湿法提铜工艺总电耗的60%以上Pb-Ca-Sn阳极电化学活性差，导致析氧过电位高槽电压高（1.82.2 V）电耗大；阳极力学性能差，导致阳极腐蚀加速电流效率降低阴极铜中含量超标[1-3]。 铅基合金电极的研究主要集中在铅酸电池板栅材料[45]。周彦保[6-10]对板栅电极添加稀土元素Sm、Ce、Pr、Nd、Y等研究，其目的寻找具有较高的析氧、析氢过电位和良好的耐腐蚀性能及强度的板栅材料。板栅材料和电积阳极两种材料均应用于高浓度硫酸体系，对耐腐蚀性的要求也是一致的，尽管在追求电化学活性即析氧过电位方面相反，但其研究结果对湿法冶金电积过程不溶性阳极材料的研究具有借鉴。洪波等[11]认为Pb-Nd合金阳极的工业前景较好。李鑫等[12]Pb-Ca-Sr-Ag(0.27%)铅基合金中添加0.03%稀土，阳极析氧过电位降低约90 mV合金硬度略有降低，但可满足电积的要求。借鉴在铅酸电池板栅材料中表现出的优良性能，将作为添加剂引入到阳极，研究其对阳极性能的影响具有重要意义采用二步重熔法制备Pb-Sm合金，分别研究电极力学性能、耐腐蚀性能及阳极电位等关键性能指标。 1 试验 1.1 Pb-Sm合金制备方法 铅基稀土合金制备存