中草药及其生长土壤中6种重金属元素含量相关性初探.pdf

6 ( , 063000) : 采用电感耦合等离子体原子发射光谱法测定了中草药中重金属元素( 铁锰铜锌 铅) 的含量, 并对中草药的生长环境土壤中重金属元素的化学形态及其分布进行了研究文中提出 了中草药样品用硝酸过氧化氢水( 5+ 2+ 1) 混合溶液消解, 并叙述了土壤样品中元素的各种形态 ( 水溶态可溶态碳酸盐结合态铁锰氧化物态有机质结合态) 的提取方法和试液结果表明: 所 测中草药中重金属元素含量明显低于土壤中元素的含量; 土壤中铁锌铜主要以有机质结合态存 在, 锰以铁锰氧化物态为主几种药材中均含有较高量的铁锰锌, 土壤中也含有较高量的有效态 铁锰锌, 说明中草药与土壤中重金属之间存在有生物迁移作用 : 中草药; 土壤; 重金属; 形态分析 : O657. 31 : A : 2010) Preliminary Exploration on Correlationship Between the Contents of 6 Heavy Metal Elements in Chinese Traditional Herbs and in their Growing Soil L U Donglian ( D ep ar tment of Chem istr y , T ang shan N or mal Colleg e, Tang s han 063000, China) Abstract: ICPAES was used i the determi atio of Fe, M , Cu, Z , Cd a d Pb i traditio al Chi ese herbs (T CHs) , a d i the study of chemical species a d distributio of the heavy metal eleme ts i their grow i g soil. Samples of T CHs w ere digestio w ith mixture of HNO H O H O( 5+ 2+ 1) . Methods for extractio of the 3 2 2 2 species ( i cludi g w atersoluble species, soluble species, combi ed carbo ate species, iro a d ma ga ese oxides species a d orga ic species) of the soil sample a d preparatio of the respect ive extract i g age t w ere described i detail. It was fou d that: the co te ts of heavy met al eleme ts fou d i T CHs w ere low er tha those i soil; the mai species of Fe, Z a d Cu w ere fou d as orga ic species, M w as fou d mai ly i mixed oxides of M a d Fe; a d the co te ts of Fe, M a d Z w ere fou d to be high both i the herbs a d i soil; a d that biological migrati g of the heavy metal eleme t s betw ee soil a d the herbs was i existe ce. Keywords: T raditio al Chi ese herbs; Soil; Heavy metal eleme ts; Speciatio a