石煤氧压酸浸提钒工艺优化-中国有色金属学报.PDFVIP

第 18 卷专辑 1 中国有色金属学报 2008 年 6 月 Vol.18 Special 1 The Chinese Journal of Nonferrous Metals Jun. 2008 文章编号：1004-0609(2008)S1-0084-04 石煤氧压酸浸提钒工艺优化 李存兄，魏 昶，李 廷，樊 刚，邓志敢 旻 ( 昆明理工大学 材料与冶金工程学院，昆明 650093) 摘 要：研究石煤一段氧压酸浸过程中硫酸亚铁添加剂对钒浸出率的影响。结果表明：在石煤氧压酸浸过程中加 入适量添加剂，钒浸出率可提高 8.5%左右。不同气体的压力酸浸实验表明，工业生产过程中，可完全用空气代替 工业氧气。采用两段氧压酸浸工艺可有效控制一段浸出液的酸度，并实现钒的选择性浸出，最终一段浸出液的酸 度可控制在 10 g/L 左右，钒浸出率可提高 10%。 关键词：石煤；钒；氧压酸浸；硫酸亚铁；浸出率 中图分类号：TF 841.3 文献标识码：A Process optimization of vanadium extraction from black shale by acidic oxidizing pressure leaching LI Cun-xiong, WEI Chang, LI Min-ting, FAN Gang, DENG Zhi-gan (School of Material and Metallurgical Engineering, Kunming University of Science and Technology, Kunming 650093, China) Abstract: The effect of ferrous sulfate on the leaching rate of vanadium by one step leaching process was carried out. The results show that with proper amount of additive the leaching rate of vanadium can be improved by 8.5%. Different gaseous pressure acid leaching experiments show that industrial oxygen can be substituted for dry air in commercial production. The acid value of first step leaching liquors can be effectively controlled at 10 g/L by using two steps leaching process, and the leaching rate of vanadium can be improved by 10%. Key words: black shale; vanadium; acid pressure leaching; ferrous sulfate; leaching rate 在我国可用于提取钒的资源主要有两种: 一钒钛 存在于云母类及高岭土等粘土矿物中，钒含量为 磁铁矿和含钒石煤矿。目前，我国生产五氧化二钒的 0.1%～8.5%。钒的存在呈现复杂性、多样化、多变化 主要资源是钒钛磁铁矿；