PtCr合金的溶液制备及其电化学性质分析SynthesisofPtCrAlloyfrom.PDFVIP

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第3 期, 245～248 ACTA CHIMICA SINICA No. 3, 245～248 ·研究论文· PtCr 合金的溶液制备及其电化学性质分析 袁 泉* 潘 牧 袁润章 (武汉理工大学材料复合新技术国家重点实验室 武汉 430070) 摘要 催化剂性能的高低直接决定了燃料电池性能的好坏. 采用Pt 基合金不仅能够降低催化剂Pt 的载量, 而且往往能 够提高催化剂的性能. 本工作用 Cr 作为合金化元素, 通过液相共沉淀的方式制备了不同比例的碳载 PtCr 合金催化剂. 采用高分辨透射电镜(HRTEM), 扫描电镜(SEM)等技术对合金催化剂的物理性质进行了测试. 结果表明, 获得的 PtCr/C 催化剂均匀地分散在Vulcan XC-72 碳载体上, 粒度小于4 nm. 通过电化学测试, 研究了不同比例PtCr 合金的电 化学催化性能. 循环伏安测试表明, 本实验条件合成的合金催化剂在Pt/Cr 原子比为2/1 的时候, 对氧还原动力学有最 佳的催化性能. 关键词 质子交换膜燃料电池; 合成; 合金; 电化学; 催化 Synthesis of PtCr Alloy from Solutions and Its Electrochemical Analysis YUAN, Quan* PAN, Mu YUAN, Run-Zhang (Sate Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070) Abstract To some extent, the behaviors of catalysts have great affection on the performance of the fuel cells. The application of Pt alloy can not only reduce consumption of Pt loaded on the catalyst layer, but also often raise catalyst performance simultaneously. Certain Pt-Cr alloys were synthesized with different atom ratio using co-precipitation and chemical reduction in aqueous phase, while high resolution transmission electron microscope (HRTEM) and scanning electron microscope (SEM) were used to assess the physical properties of these alloys. From the results, the PtCr alloy could be observed to be uniformly deposited on the carbons and the diameters of alloy particle