{culzn·culzn-h2o·h2o}n的合成-中国科学.pdfVIP

B 2006, 36 (1): 47~52 47 1D {[CuLZn·CuLZn- * (H O)]·H O} 2 2 n ** (, 475001; , 130022) , IR , X . {[CuLZn·CuLZn(H O)]·H O} (H L=N-(3-)-N′-(2- 2 2 n 4 )), , 1D . , Osa [1~6]. , [1,2], [7~9], . , , [1~4], . . [14~16], “”[10,11], -COOH , , . , . Schiff , H L, K CuL·H O; 4 2 2 Schiff, , , K CuL·H OZn(OAC) 2 2 , , 1D -{[CuLZn· CuLZn(H2 O)] [12,13]. ·H O} . 2 n 2005-04-28; : 2005-08-03 * (0311020800)(2002150003) ** E-mail: rjtao@ SCIENCE IN CHINA Ser. B Chemistry 48 B