铜渣熔融还原过程中硫的行为特征研究-有色金属科学与工程.docVIP

铜渣熔融还原过程中硫的行为特征 李磊 ，王华，胡建杭 （昆明理工大学，冶金与能源工程学院，冶金节能减排教育部工程研究中心，云南省复杂有色金属资源清洁利用国家重点实验室云南昆明，6500930.8增至1.4，0.6%降至0.13%TF 046 文献标志码：A Sulfur Behavior Characteristics in the Process of Copper Slags Smelting Reduction LI Lei, WANG Hua, HU Jian-hang (Engineering Research Center of Metallurgical Energy Conservation Emission Reduction, State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Ministry of Education, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, China) Abstract: The sulfur behavior characteristic in the process of copper slags smelting reduction was studied in this paper. When slag basicity increased from 0.8 to 1.4, the slag sulfur capacity and desulphurizing capacity increased, and the molten iron sulfur content decreased from 0.6% to 0.13%.Desulfurization reaction of molten iron is endothermic, and the molten iron sulfur content decreased from 0.13% to 0.089% with the holding temperature increasing from 1773 K to 1823 K. The theoretical?sulfur distribution ratio between molten slag and iron was higher than the real under the test time, and the desulfurization rates of the molten iron increased with the holding time. Sulfur content of the molten iron was decreased to 0.11% treated in the condition of holding temperature of 1823 K, residence time of 40 minutes, and slag basicity of 1.4. The iron sulfur content is still high, and the generated iron needed desulphurization pretreatment for steelmaking. Keywords: copper slags; smelting reduction; sulfur behavior characteristics; waste utilization 0前 言 铜渣氧主要O·SiO2）和磁铁矿（Fe3O4）[7]，针对其的回收主要有高温熔融氧化-常温破碎磁选法、阶段磨矿阶段选别法和直接熔融还原法三种。高温熔融氧化-常温破碎磁选工艺中，向熔融铜渣中吹入空气并在冷却过程中控制一定降温速率 [8]，渣中磁铁矿富集率可提高到85% [9]，但反应后期熔渣粘度升高，磁铁矿相继续聚集长大受阻，铁收得率总体较低。阶段磨矿阶段选别工艺中，铁硅酸盐在磁选过程中进入尾矿，铁回收率亦较低[10-12]。倪文马明生.1 实验原料 实验所用原料为某铜冶炼厂水淬铜渣，化学组成见表XRD pattern of original copper residue 组分 Fe CaO SiO2 Al2O3 MgO Cu S Others 含量 (wt%) 38.55 2.77 34.08 3.90 1.14 1.06 0.52 14.