使溴水和kmno4褪色的有机物的条件（The organic bromine and KMnO4 fading conditions）.docVIP

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使溴水和kmno4褪色的有机物的条件（The organic bromine and KMnO4 fading conditions）.doc

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使溴水和kmno4褪色的有机物的条件（The organic bromine and KMnO4 fading conditions）

使溴水和kmno4褪色的有机物的条件（The organic bromine and KMnO4 fading conditions） Induction can make Potassium Permanganate solution fade, all kinds of material can make water fade Bromine and Potassium Permanganate solution is often used as test reagents of some organic compounds in organic chemistry reaction to identification or identification of some organic compounds in solution color change. (1) can make water fade or change material and chemical reaction principle respectively: The alkene, alkyne, dienes and other unsaturated hydrocarbon reaction, make water fade CH2=CH2+Br2 - CH2Br-CH2Br CH = CH+Br2 - - CHBr=CHBr (or CH = CH+2Br2 - - CHBr2-CHBr2 CH2=CH-CH=CH2+Br2 - CH2Br-CH=CH-CH2Br (or CH2=CH-CH=CH2+Br2 - to CH2Br-CHBr-CH=CH2) React with phenol to form white precipitate The reaction with aldehydes such as substances with aldehyde, the bromine water fade CH3CHO+Br2+H2O=CH3COOH+2HBr The benzene, toluene, carbon tetrachloride and other organic solution for extraction of the oscillation, the organic solvent to dissolve the bromine bromine faded orange (or red brown). With the alkaline solution (NaOH solution and Na2CO3 solution) reaction, the bromine fade. Br2+2NaOH=NaBr+NaBrO+H2O (or 3Br2+6NaOH=5NaBr+NaBrO3+3H2O) Br2+Na2CO3=NaBr+NaBrO+CO2 With the strong inorganic reductant (such as H2S, SO2, KI and FeSO4) reaction, make water fade. Br2+H2S=2HBr+S: (light yellow precipitate) Br2+SO2+2H2O=2HBr+H2SO4 3Br2+6FeSO4=2Fe2 (SO4) 3+2FeBr3 Br2+2KI=2KBr+I2 (solution becomes Brown) (2) the Potassium Permanganate solution. Material and related chemical reaction principle respectively: With alkenes, alkynes, dienes and other unsaturated hydrocarbon reaction, the Potassium Permanganate solution and fade; benzene (toluene, ethylbenzene, xylene) reaction, make Potassium Permanganate acid solution. The phenol and redox reaction, make Potassium Permanganate solution. The organic matter and aldehyde aldehyde redox reactions occur, the Potassium Permanganate solution. With the reduction of inorg