傅里叶红外ft-ir 基础培训+nicolet 6700.pptVIP

Basic FT-IR Theory  System Design Table of contents 什么样的物质有红外吸收 红外谱图与分子结构如何对应 怎样的仪器结构才能满足红外分析要求 什么是FTIR NICOLET 6700的结构 什么是ATR FT-IR的联机技术 光分析法 光波能量 分子中基团的基本振动形式 basic vibration of the group in molecular 分子振动方程式 Selection Rules for Infrared Activity To absorb energy, the DIPOLE must change when the transition occurs The intensity of the absorption is proportional to the magnitude of the dipole CHANGE 红外光谱与有机化合物结构 峰位、峰数与峰强 峰强 Polyatomic Molecules The spectrum becomes more complex as the number of bonds increases 红外光谱信息区 指纹区(1350 ? 650 cm-1 ) , 常见基团的红外吸收带 红外光谱仪的分类 红外分光光度法是鉴别物质和分析物质结构的有用手段 Components of an Infrared Spectrometer 红外光谱仪主要部件 傅里叶变换红外光谱仪工作原理图 FT-IR的优点 多元化优点 (Felgett’s) 所有波长同时测量 高光通量优点 (Jacquinot’s) 更高的能量通过 (更大的光栏) 不需要分光，信号强，灵敏度很高 高精度优点 (Connes’) 内部校正源自He-Ne 激光 (精度 = 0.01 cm-1) 扫描速度极快(1s) 适合仪器联用 根据应用选择光源、分束器以及检测器的不同组合 Signal at the Detector Wave Interactions (Interference) In Phase Constructive Interference Out of Phase Destructive interference The Interferogram Michelson干涉仪工作原理图 Fast Fourier Transformation快速傅立叶变换（FFT） Transmission Spectrum 透射谱图 NICOLET 6700 迈克尔逊干涉仪动态调整技术（DA） Nexus Smart Technology Smart Accessories Fourier Transform Spectroscopy Specular Reflectance Diffuse Reflectance - DRIFTS Transmission Attenuated Total Reflectance - ATR 智能型Omni(欧米)采样附件 Diffuse Reflectance Kubelka-Munk Theory Transmission Analysis Solids, Liquids, Gases Customized pathlength Strong Absorbers - Short Pathlength Weak absorbers - Long Pathlength Qualitative Analysis Quantitative Analysis Requires Sample Preparation Attenuated Total Reflectance non-destructive method for IR analysis no sample preparation is required for the surface of the sample Depth of Penetration Refractive index of ATR element Angle of incidence of ATR element Refractive index of sample Wavelength Diamond as an ATR Material Hard surface, resistant to scratching and surface damage - including intractable solids Chemically inert - handles corrosive materials, such as strong aci