Co取代介孔磷铝分子筛的合成表征及催化性能-中国有色金属学报.PDF

19 11 2009 11 Vol.19 No.11 The Chinese Journal of Nonferrous Metals Nov. 2009 1004-0609(2009)11-2061-06 Co 12 (1. 210094 2. 250353) Co H2O2 H2O2 3 5%70 4 h 42.2%82.0% 34.6% Co TQ 426 A Synthesis, characterization and catalytic performance of Co-substituted mesoporous aluminophosphate molecular sieves 1 2 LI Xin-zhu , ZHANG Ji-shi (1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; 2. School of Light Chemistry and Environment Engineering, Shandong Institute of Light Industry, Ji’nan 250353, China) Abstract: The Co-substituted mesoporous aluminophosphate molecular sieve (Co-MAP) was prepared by hydrothermal crystallizing process under alkaline conditions using cetyltrimethylammonium chloride as the templating agent. The influences of solvents, reaction temperature, reaction time, amount of catalyst and mole ratio of H O to styrene were also 2 2 studied. The results show that, under the conditions of n(H O )/n(styrene)=3, catalyst of 5%, reaction temperature of 2 2 70 and reaction time of 4 h, the conversion rate of styrene, the selectivity to benzaldehyde and the yield of benzaldehyde reach 42.2%, 82.0% and 34.6%, respectively. Key words: mesoporous aluminophosphate molecular sieve; cobalt; styre