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Hindawi Publishing Corporation Advances in Materials Science and Engineering Volume 2011, Article ID 402376, 11 pages doi:10.1155/2011/402376 Research Article Crystallization Behavior and Microstructural Analysis of Lead-Rich (Pbx Sr1−x ) TiO3 Glass Ceramics Containing 1 mole % La2O3 C. R. Gautam,1, 2 Devendra Kumar,1, 2 and Om Parkash1, 2 1 Department of Physics, University of Lucknow, Lucknow 226007, India 2 Department of Ceramic Engineering, Institute of Technology, Banaras Hindu University, Varanasi 221005, India Correspondence should be addressed to C. R. Gautam, gautam ceramic@ Received 1 March 2011; Accepted 15 June 2011 Academic Editor: Joseph Lai Copyright © 2011 C. R. Gautam et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Solid solution of perovskite Pb,SrTiO3 in Pb-rich composition can be crystallized in borosilicate glassy matrix. The addition of rare earth and transition metal oxides is known to influence the crystallization behavior and surface morphology of perovskite crystallites in glassy matrix. In the present paper, the glasses in the lead-rich system 64[(Pb Sr )·TiO ]-25[2SiO ·B O ]-5[K O]- x 1−x 3 2 2 3 2 5[BaO] (1 ≤ x ≤ 0.5) with the addition of 1 mol % La O were prepared to study its effect on their crystallization behavior. 2 3 Differential thermal analysis (DTA) patterns show one or more exothermic crystallization sharp peaks, which shift towards hi