catalytic reduction of benzaldehyde under hydrogen flow over nickel-containing mesoporous silica catalysts苯甲醛的催化还原氢溢出nickel-containing介孔二氧化硅催化剂.pdfVIP

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catalytic reduction of benzaldehyde under hydrogen flow over nickel-containing mesoporous silica catalysts苯甲醛的催化还原氢溢出nickel-containing介孔二氧化硅催化剂.pdf

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catalytic reduction of benzaldehyde under hydrogen flow over nickel-containing mesoporous silica catalysts苯甲醛的催化还原氢溢出nickel-containing介孔二氧化硅催化剂

Open Journal of Physical Chemistry , 2012, 2, 73-80 /10.4236/ojpc.2012.21010 Published Online February 2012 (http://www.SciRP.org/journal/ojpc) Catalytic Reduction of Benzaldehyde under Hydrogen Flow over Nickel-Containing Mesoporous Silica Catalysts 1 1 1,2 1 1 Adel Saadi , Kahina Lanasri , Khaldoun Bachari , Djamila Halliche , Chérifa Rabia 1Laboratoire de Chimie du Gaz Naturel, Faculty of Chemistry, University of Sciences and Technology Houari Boumediene, Algiers, Algeria 2Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques, Algiers, Algeria Email: asaadi@usthb.dz Received October 28, 2011; revised November 29, 2011; accepted December 29, 2011 ABSTRACT The hydrogenation of benzaldehyde over a series of nickel-containing mesoporous silicas with different nickel contents was studied at atmospheric pressure in the range temperature of 393 - 513 K under H2 ﬂow. These materials (noted Nin-HMS with n = Si/Ni = 50, 25, 15) have been prepared at room temperature using a route based on hydrogen bond- 0 0 ing and self-assembly between neutral primary amine micelles (S ) and neutral inorganic precursors (I ). They were characterized by their chemical analysis, BET surface area, XRD, FT-IR, and SEM microscopy. The obtained products were benzylalcohol, toluene, benzene with yields depending on the nickel content (Si/Ni ratio) and reaction temperature. The products of benzaldehyde hydrogenation (benzylalcohol, and toluene