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chiral palladium complexes based on derivatives of benzylamine and 2α-hydroxypinan-3-one手性钯配合物基于衍生品的苄胺和2α-hydroxypinan-3-one.pdf

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chiral palladium complexes based on derivatives of benzylamine and 2α-hydroxypinan-3-one手性钯配合物基于衍生品的苄胺和2α-hydroxypinan-3-one

Vol.2, No.11, 1189-1194 (2010) Natural Science /10.4236/ns.2010.211147 Chiral palladium complexes based on derivatives of benzylamine and 2α-hydroxypinan-3-one a b,* b b Olga A. Zalevskaya , Yana A. Gureva , Larisa L. Frolova , Igor N. Alekseev , Alexander V. Kutchinb a Syktyvkar State University, Syktyvkar, Petrozavodskaja, Syktyvkar, Russia b Institute of Chemistry of Komi Scientific Centre, Ural Branch of Russian Academy of Sciences, Pervomaiskaja, Syktyvkar, Russia; *Corresponding author: gurjeva-ja@chemi.komisc.ru Received 30 July 2010; revised 2 September 2010; accepted 5 September 2010. ABSTRACT chiral ligands remains an important problem. Synthesized and characterized new chiral palla- 2. EXPERIMENTAL dium complexes, some of which contain asym- metric donor nitrogen atom. Nitrogen-containing 2.1. General derivatives (+) - and (-)-2α-hydroxypinan-3-one- (1R,2R,5R)-3-(benzylimino)-2,6,6-trimethylbicy- The 1H and 13C NMR spectra were recorded with a 1 Bruker Avance-300 spectrometer operating at the fre- clo[3.1.1]heptane-2-ol (HL ), (1S,2S,3S,5S)-3- (benzylamino)-2,6, 6-trimethylbicyclo[3.1.1]- quencies 300 and 75 MHz for 1H and 13C nucleus, re- 2 spectively. The measurements were carried out at ambi- heptane-2-ol (HL ), (1R,2R,5R)-3-((S)-α-methyl- benzylimino)-2,6,6-trimethylbicyclo[3.1.1]- ent temperature