原创力文档co-liquefaction of coal and used tire in supercritical waterco-liquefaction煤炭和轮胎用于超临界水.pdfVIP
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co-liquefaction of coal and used tire in supercritical waterco-liquefaction煤炭和轮胎用于超临界水
Energy and Power Engineering, 2010, 2, 95-102 95
doi:10.4236/epe.2010.22014 Published Online May 2010 (http://www.SciRP.org/journal/epe)
Co-liquefaction of Coal and Used Tire in
Supercritical Water
1 1,2 1,2*
Kwanruthai Onsri , Pattarapan Prasassarakich , Somkiat Ngamprasertsith
1
Fuels Research Center, Department of Chemical Technology, Faculty of Science,
Chulalongkorn University, Bangkok, Thailand
2Center for Petroleum, Petrochemicals and Advance Materials, Chulalongkorn University,
Bangkok, Thailand
E-mail : somkiat.n@chula.ac.th
Received December 19, 2009; revised January 8, 2010; accepted March 3, 2010
Abstract
The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical
water under a nitrogen atmosphere to investigate the effects of temperature (380-440 ℃), water/feedstock
ratio (4/1-10/1 (wt./wt.)) and the % used tire content in the feedstock (0-100 wt.%) on the conversion effi-
ciency, liquid yield and oil composition attained. The maximum conversion and oil yield were 67 and 50%,
respectively, obtained at 400 ℃ at 1 min, with water/feedstock ratio of 10/1 and 80% used tire content. The
distillation characteristics of the oil products, analyzed by simulated distillation gas chromatography, re-
vealed that the oil composition depended significantly on the reaction temperature. The co-liquefaction o
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