comparison of chromatographic performance for l-phenylalanine-derived organic phases on silica by “grafting from” and “grafting to” strategies比较色谱性能l-phenylalanine-derived有机相二氧化硅的u201c嫁接u201d和u201c嫁接u201d策略.pdfVIP

下载本文档

5
0
约9.12万字
约 14页
2017-08-27 发布于上海
举报
版权申诉

comparison of chromatographic performance for l-phenylalanine-derived organic phases on silica by “grafting from” and “grafting to” strategies比较色谱性能l-phenylalanine-derived有机相二氧化硅的u201c嫁接u201d和u201c嫁接u201d策略.pdf

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

comparison of chromatographic performance for l-phenylalanine-derived organic phases on silica by “grafting from” and “grafting to” strategies比较色谱性能l-phenylalanine-derived有机相二氧化硅的u201c嫁接u201d和u201c嫁接u201d策略

American Journal of Analytical Chemistry , 2011, 2, 795-808 doi:10.4236/ajac.2011.27091 Published Online November 2011 (http://www.SciRP.org/journal/ajac) Comparison of Chromatographic Performance for L-Phenylalanine-Derived Organic Phases on Silica by “Grafting from” and “Grafting to” Strategies 1,2* 2 2 Mohammed Mizanur Rahman , Makoto Takafuji , Hirotaka Ihara 1 Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering and Technology, University of Dhaka, Dhaka, Bangladesh 2Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, Kumamoto , Japan * E-mail : mizan607@ Received April 30, 2011; revised June 7, 2011; accepted June 24, 2011 Abstract α L-phenylalanine-derived polymerizable organogel, N ’-octadecyl-N -(4-vinyl)-benzoyl-L-phenylalanineami- de (4) has been prepared according to the procedure described elsewhere. Compound 4 was successfully po- lymerized by surface initiated atom transfer radical polymerization (ATRP) from the initiator grafted silica particles (sil-poly4). It was also telomerized with 3-mercaptopropyltrimethoxysilane (MPS) and the telomer (T4) was grafted on to silica (sil-T4). TGA and elemental analysis measurement revealed that higher amount of polymer can graft by ATRP process than that of “grafting to” strategy. The results of 13C CP/MAS NMR measurement showed that the N-alkyl chain of the grafted polymers for both sil-poly4