determination of melamine in fresh milk by electrochemistry with solid phase microextraction at bismuthyl chloride modified graphite epoxy composite electrode新鲜牛奶中三聚氰胺的电化学测定固相微萃取在bismuthyl氯化改性石墨环氧复合电极.pdfVIP

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determination of melamine in fresh milk by electrochemistry with solid phase microextraction at bismuthyl chloride modified graphite epoxy composite electrode新鲜牛奶中三聚氰胺的电化学测定固相微萃取在bismuthyl氯化改性石墨环氧复合电极.pdf

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determination of melamine in fresh milk by electrochemistry with solid phase microextraction at bismuthyl chloride modified graphite epoxy composite electrode新鲜牛奶中三聚氰胺的电化学测定固相微萃取在bismuthyl氯化改性石墨环氧复合电极

American Journal of Analytical Chemistry , 2011, 2, 612-618 doi:10.4236/ajac.2011.25069 Published Online September 2011 (http://www.SciRP.org/journal/ajac) Determination of Melamine in Fresh Milk by Electrochemistry with Solid Phase Microextraction at Bismuthyl Chloride Modified Graphite Epoxy Composite Electrode 1* 1 2 1 1 1 Yongchun Zhu , Yanjia Zhang , Jingyi Li , Yanli Han , Guobin Dong , Hongbo Zhang 1College of Chemistry and Life Science, Shenyang Normal University, Shenyang, China 2Foreign Language Department, Shenyang Agricultural University, Shenyang, China * E-mail : yongchunzhu@ 126.com, yongchunzhu@ 126.com Received April 28, 2011; revised May 3, 2011; accepted June 7, 2011 Abstract Melamine as an important chemical raw material and a harmful additive in foods has attracted many people’s attention. In the present paper, The graphite-epoxy composited solid phase electrode was modified with bis- muth layer by cyclic voltammetric deposition of bismuth from Bi(NO 3 3) aqueous solution including 0.10 M HNO3, and hydrolyzed into micro bismuthyl chloride on-sites. Melamine in fresh milk was extracted with solid phase micro-extraction on the bismuthyl chloride modified graphite-epoxy composited solid electrode. The adsorption of melamine on bismuthyl chloride particle surfaces follows a Freundlich adsorption model, and results in the decrease of the reduction peak current of bismuth in bismuthyl chloride, and determined by differential pulse vol