微波水热晶化制备纳米二氧化钛光催化剂及其性能-高校化学工程学报.PDF

20 1 No.1 Vol.20 2006 2 Journal of Chemical Engineering of Chinese Universities Feb. 2006 1003-9015(2006)01-0138-04 1 1,2 , ( 1. , 2. , 710049) TiCl TiO XRDTEMTG-DTA 4 2 TiO 2 5 20×10 Pa Ti(OH) 2.5 h 10 nm 4 TiO 2 TQ426.81 A Study on Nanocrystal Titanium Dioxide Catalyst Prepared by Microwave-Hydrothermal Method CHONG Fa-guo1, ZHAO Jing-lian1,2 (1. Department of Chemical Engineering, 2. Department of Environmental Engineering, Xi’an Jiaotong University, Xi’an 710049, China) Abstract Using titanium tetrachloride as the raw material, the nano-crystal titanium dioxide was synthesized by microwave-hydrothermal method. All products were characterized by X-ray diffraction (XRD)TG-DTA and transmission electron microscopy (TEM). Their catalytic capability was investigated by the degradation of acid-fuchsin. The results suggest that the microwave field makes the hydrothermal reaction system reaches a high temperature rapidly and uniformly, and crystallization is accelerated. When Ti(OH)4 is treated for 2.5h at 20×105 Pa in a microwave-hydrothermal vessel, the main crystalline phase of titanium dioxide is anatase and the particle size is under 10 nm. Due to the generation of high temperatures rapidly in th