不同粒级的煤胶体对汞的吸附动力学-环境工程学报.pdfVIP

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 不同粒级的煤胶体对汞的吸附动力学 ∗ 薛杨,邱素芬,许端平 ,赵晓亮,吴志军,刘嘉欣 辽宁工程技术大学环境科学与工程学院,阜新 123000 摘　 要　 为了解煤胶体对汞的吸附动力学特性,采用沉降法和离心法提取由霍林河采集煤样中的煤胶体(0 ~2、2 ~5、5 ~ 10 μm),采用批量实验对不同粒径和不同温度下,煤胶体对汞的吸附动力学特性进行了研究。 结果表明:煤胶体对汞的吸 附反应为吸热反应,以化学吸附为主,其吸附动力学过程可用准二级动力学方程和双室模型很好的描述。 煤胶体对汞的平 衡吸附量随粒径的减小和温度的升高而逐渐增大,不同粒径煤胶体受温度影响的大小关系为(5 ~10)μm (2 ~5)μm (0 ~2)μm。 煤胶体对汞的吸附从初始阶段到达到表观平衡,快速吸附均占据优势。 在表观平衡时,粒径越大,快速吸附的 贡献率越小。 煤胶体对汞的吸附反应速率随温度升高和粒径减小而增大。 温度越高、粒径越小,快速吸附速率越大;而慢 速吸附速率则随温度升高和粒径增大而增大。 汞在0 ~2 μm 和2 ~5 μm 煤胶体上的吸附过程,粒内扩散是其主要控速步 骤;而对于5 ~10 μm 的煤胶体,膜扩散是主要控速步骤。 关键词　 煤胶体;汞;吸附动力学;粒径;双室一级动力学模型 中图分类号　 X53　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-3187-08　　 DOI　 10.12030/ j.cjee.201608100 Adsorption kinetics of mercury on different particle-size colloids from coal ∗ XUE Yang,QIU Sufen,XU Duanping ,ZHAO Xiaoliang,WU Zhijun,LIU Jiaxin College of Environmental Science and Engineering,Liaoning Technology University,Fuxin 123000,China Abstract　 Coal samples were collected from Huolinhe Coal Mining Group in Inner Mongolia,China,and three colloid particle sizes (0 to2,2 to5,and5 to 10 μm) were extracted. We carried out batch experiments to study the adsorption kinetics of mercury on colloid from coal. Additionally,we tested the effects of colloid particle size and temperature on adsorption behaviors. The results showed that the adsorption of mercury on colloid (0 to 2 μm) was endothermic and most part of that was chemical. In addition,this adsorption was well described by a pseudo-second-order model and a two-compartment (fast and slow) first-order model. The adsorption amounts increased inversely with colloid particle size. In all adsorption systems,mercury adsorption was enhanced when temperature increased from 25 to 45 ℃. The effect of