交联副产物对交联聚乙烯中空间电荷行为的影响.pdfVIP

第 35 卷 第 11 期 中 国 电 机 工 程 学 报 Vol.35 No.11 Jun. 5, 2015 2015 年 6 月 5 日 Proceedings of the CSEE ©2015 Chin.Soc for Elec.Eng. 2903 DOI ：10.13334/j.0258-8013.pcsee.2015.11.031 文章编号：0258-8013 (2015) 11-2903-08 中图分类号：TM 85 交联副产物对交联聚乙烯中空间电荷行为的影响 钟琼霞，兰莉，吴建东，尹毅 (上海交通大学电气工程系，上海市 闵行区 200240) The Influence of Cross-linked By-products on Space Charge Behaviour in XLPE ZHONG Qiongxia, LAN Li, WU Jiandong, YIN Yi (School of Electrical Engineering, Shanghai Jiao Tong University, Minhang District, Shanghai 200240, China) ABSTRACT: To study the relationship between cross-linked 烯试样在直流预压后的空间电荷分布，并通过气相色谱–质 by-products of cross-linked polyethylene (XLPE) and space 谱联用仪测试了 3 种试样内部交联副产物的残余量。研究表 charge characteristics under high voltage direct current 明：随着脱气时间的延长，试样内部的交联副产物种类没有 (HVDC), three kinds of XLPE samples were degassed for 改变，但每种副产物的残余量均明显减少。未脱气试样在直 various hours (0h, 24h, 72h). Space charge distribution in these 流高压下，靠近两侧电极处均积累了大量的异极性电荷，并 samples was detected after DC was applied. The measurement 且电荷量随着电场升高明显增多。试样经过脱气处理后，内 was based on pulsed electro-acoustic measurement (PEA) 部积累的空间电荷量明显减少。低电场下电极附近仅观察到 principle. The remaining cross-linked by-products in the 少量的同极性电荷，当电场升高后，异极性电荷逐渐代替同 极性电荷成为主导。这说明，交联聚乙烯材料内部的异极性 samples were detected by gas chromatograph-mass 电荷主要来源于直流电场下交联副产物的解离，并且电场越 spectrometer (GC-MS). It shows that with the increase of 高，副产物解离形成的离子电荷越多。脱气处理能有效减少 degassing time, the kinds of cross-linked by-products